The photochemical aspects of air pollution are reviewed through 1964. The topics covered include: nitric oxide oxidation and inorganic reactions, atomic oxygen and ozone reactions, singlet oxygen and its importance to air pollution, aldehyde and ketone photolysis, sulfur dioxide photolysis, synergistic effects, photooxidation of commercial solvents, product formation with emphasis on hydroperoxides, nitric acid and peroxybenzoyl nitrate, reactivity measurements including hydrocarbon consumption, nitric oxide oxidation, oxidant formation and eye irritation, aerosols, natural pollution, and actinometry. The effects of photochemical pollutants on plants are not covered. Suggestions for future research are also given.