We investigate the light deflection in the weak field approximation from the accelerating charged AdS black hole. For this purpose, we apply the Gauss–Bonnet theorem to calculate the light deflection in the weak field area and use the Gibbons–Werner approach to analyze the optical geometry of the accelerating charged AdS black hole in the non-magnetic plasma absence/presence of a non-magnetic medium. We also represent the graphical behavior of the light deflection angle w.r.t. the impact parameter. We also compute the light deflection angle using Keeton and Petters approximations under the impact of accelerating charged AdS black hole geometry. Furthermore, by using the ray-tracing approach, we determine the shadow in the non-magnetic plasma presence and also demonstrate that graphical shadow has an impact on the gauge potential, non-magnetic plasma frequencies and charge.