Study of CuII binuclear complexes of binucleating hexadentate ligands

Reactions of CuSCN with tetramethylthiuram &sulfide in CH3CN in the presence of styrene and N.N.N'.N",N"-pentarnethyldiethylenetriamine gave rise to a new copper(1) complex of N,W-dimethyldithiocabamate ( [CU(S,CNM~~]~),. The title compound crystallized in the triclinic P-1 space group with lattice parameters a=0.7610(4) nrn, b=0.8911(4) nm. c=0.9268(5) nm. a=68.66(1)", p =83.88(2)", y=79.31(2)", V= 0.5748(5) nm3, Z = 2 . The compound has a unique 1D chain smcture composed of CuSCSCuSCS eight-membered rings and a pair of C U S bonds, the structure of which has been determined by singlecrystal X-ray crystallography.The isolation of this compound may provide some helpful information for the cause of the induction periods of the reverse atom transfer radical polymerization.

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Synthesis and crystal structure of N,N′‐dimethyldithio‐arbamato‐copper(I) polymer {[Cu(Me₂dtc)]₂}_n

Zhang

Zhu

Cheng

et al. 2004

Chin. J. Chem.

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Highly Selective and Sensitive Colorimetric and Fluorescent Chemosensor for Rapid Detection of Ag+, Cu2+ and Hg2+ Based on a Simple Schiff Base

Zhang

Niu

et al. 2016

J Fluoresc

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A new reversible colorimetric and fluorescent chemosensor MMIP based on a simple Schiff base has been successfully synthesized. MMIP exhibited high selectivity and sensitivity towards Ag, Cu and Hg ions with a short response time in DMSO/HO (1/1, v/v) solution among various metal ions, and the results could be monitored directly by naked eyes. The binding stoichiometry between MMIP and Ag/Hg/Cu has been determined to be 1:2 by Job's plot and FT-IR analysis. MMIP could effectively detect Ag, Cu and Hg over a wide pH range of 3-10. The good linear correlations were obtained in the concentration ranges of 0-20 μM for Ag, Cu and Hg. Thus sensor MMIP could be potentially used for the quantification of Ag, Cu and Hg in aqueous solution.

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The crystal structure, equilibrium and spectroscopic studies of bis(dialkyldithiocarbamate) copper(II) complexes [Cu2(R2dtc)4] (dtc=dithiocarbamate)

et al. 1999

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Study of CuII binuclear complexes of binucleating hexadentate ligands

Cited by 4 publications

References 19 publications

Synthesis and crystal structure of N,N′‐dimethyldithio‐arbamato‐copper(I) polymer {[Cu(Me₂dtc)]₂}_n

Synthesis and crystal structure of N,N′‐dimethyldithio‐arbamato‐copper(I) polymer {[Cu(Me₂dtc)]₂}_n

Highly Selective and Sensitive Colorimetric and Fluorescent Chemosensor for Rapid Detection of Ag+, Cu2+ and Hg2+ Based on a Simple Schiff Base

The crystal structure, equilibrium and spectroscopic studies of bis(dialkyldithiocarbamate) copper(II) complexes [Cu2(R2dtc)4] (dtc=dithiocarbamate)

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Study of CuII binuclear complexes of binucleating hexadentate ligands

Cited by 4 publications

References 19 publications

Synthesis and crystal structure of N,N′‐dimethyldithio‐arbamato‐copper(I) polymer {[Cu(Me2dtc)]2}n

Synthesis and crystal structure of N,N′‐dimethyldithio‐arbamato‐copper(I) polymer {[Cu(Me2dtc)]2}n

Highly Selective and Sensitive Colorimetric and Fluorescent Chemosensor for Rapid Detection of Ag+, Cu2+ and Hg2+ Based on a Simple Schiff Base

The crystal structure, equilibrium and spectroscopic studies of bis(dialkyldithiocarbamate) copper(II) complexes [Cu2(R2dtc)4] (dtc=dithiocarbamate)

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Product

Resources

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Synthesis and crystal structure of N,N′‐dimethyldithio‐arbamato‐copper(I) polymer {[Cu(Me₂dtc)]₂}_n

Synthesis and crystal structure of N,N′‐dimethyldithio‐arbamato‐copper(I) polymer {[Cu(Me₂dtc)]₂}_n