Study of Iron-Based Catalysts Performance in Fischer – Tropsch Synthesis: Temperature and Promoter Effect

Abstract

The full text of the article will be published in the English version of the journal "Catalysis in Industry" No. 1, 2023.The iron-based catalysts were prepared via wet-impregnation method. The composition of the final iron catalysts, regarding to the weight ratio is as follow 14%Fe/γ-Al2O3, 14%Fe/3%Cu/γ-Al2O3, 14%Fe/3%Sn/γ-Al2O3 and 14%Fe/3%Cu/1%Sn/γ-Al2O3. The catalysts were characterized using XRD, ICP, BET, H2-TPR, FE-SEM and EDX techniques. The catalytic activity was evaluated in a fixed bed reactor under 20 bar of pressure, H2/CO = 1, GHSV = 2 L/(gcat·h), in the temperature range of 270–300 °C. Then, the effect of temperature and promoters (Cu and Sn) on the catalyst performance were investigated. CO conversion and product selectivity were also calculated using the results of GC. The results showed that the Cu and Sn promoters increased the reduction rate of Fe2O3 by providing H2 dissociation sites. Higher temperatures were also shown to change the CO conversion and product selectivity. The selectivity of both methane and C2–C4 hydrocarbons decreased while the selectivity of C5+ increased because of simultaneous use of Cu and Sn for promoting iron catalyst. Sn promoter increased FT and WGS activities.

Investigation of Mn and Ca promoter effects in iron-based catalysts: CO hydrogenation reaction

“…This indicates that Fe (NO 3 ) 3 ·9H 2 O oxidized and decomposed to hematite during the calcination treatment at 400 °C. 5,29 The XRD patterns of all samples were compared with the characteristics of Fe 2 O 3 patterns based on the reference code 00-033-0664 (ICDD). Also, based on the reference code 00-010-0173 (ICSD 60419), some typical reflections attributed to the primary support, γ-Al 2 O 3 , were identified by approximating the peaks in the 2 θ ranges given in Table 1.…”