“…Glass film formation under HTA is also a multi-stage process that includes several solid-phase reactions occurring in a wide range of temperatures [ 1 , 3 , 7 , 8 , 9 ]. The formation of GOES surface structure begins as oxidation during DA [ 3 , 7 , 8 , 9 , 10 , 11 , 12 , 13 , 14 , 15 , 16 ]. An ultrathin layer, mainly consisting of silicon oxide SiO 2 coated with (FeMn)SiO 3 /(FeMn) 2 SiO 4 shells, forms on the steel surface after DA [ 12 , 13 ].…”