Subsolidus Phase Relations of the SrO-In2O3-CuO System in Air

Grivel, Jean‐Claude; Thydén, Karl Tor Sune

doi:10.1007/s11669-013-0187-4

Cited by 4 publications

(1 citation statement)

References 37 publications

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“…In Figure 1, the pure components A, B, and C are located at the corners, and the formation of the compounds AB, AB 2 , CB, and AC is shown in their respective binary systems. One example found in the literature is the work by Grivel and Thyden, 42 who describe the ternary system SrO−In 2 O 3 −CuO at 900 °C in air, with analogous binary oxides such as Sr 2 CuO 3 , In 2 Cu 2 O 5 , SrIn 2 O 4 , SrCuO 2 , etc. at the three sides of the ternary system.…”

Section: Discussionmentioning

confidence: 99%

Phase Relations in Ternary Systems in the Subsolidus Region: Methods To Formulate Solid Solution Equations and To Find Particular Compositions

et al. 2017

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A good understanding of ternary phase diagrams is required to advance and/or to reproduce experimental research in solid-state and materials chemistry. The aim of this paper is to describe the solutions to problems that appear when studying or determining ternary phase diagrams. A brief description of the principal features shown in phase diagrams of ternary systems in the subsolidus region is included. We present a systematic procedure to obtain specific compositions of particular interest as well as to calculate binary and ternary ratios of compounds inside the Gibbs triangle and a step-by-step methodology to formulate solid solution equations in binary, ternary, or higher-composition compounds. Specific problems and their solutions are presented as a practical guide, linking the learned concepts with their applications in ceramics and solid-state chemistry research. In addition, ready-to-go exercises with worked-out solutions are included for practice. The procedures described herein may be helpful to those interested in phase diagram interpretation, preparation, and analysis.

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Section: Discussionmentioning

confidence: 99%

Phase Relations in Ternary Systems in the Subsolidus Region: Methods To Formulate Solid Solution Equations and To Find Particular Compositions

et al. 2017

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Subsolidus Phase Relations of the CaO-REOx -CuO Systems (RE = Eu, Tb, Dy, Ho, Er, Lu and Sc) at 900 °C in Air

Grivel

2016

J. Phase Equilib. Diffus.

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Subsolidus Phase Relations of the CoOx-CuO-SrO System

Grivel

2017

J. Phase Equilib. Diffus.

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AbtractThe subsolidus phase relations of the CoO x -CuO -SrO system were investigated in air. The samples were equilibrated at 900C. The pseudo-ternary section contains three stoichiometric binary oxide phases (Sr 2 CuO 3 , SrCuO 2 and Sr 14 Cu 24 O 41-δ ) and a binary oxide solid solution: Sr 6+x Co 5 O 15+δ (0 ≤ x ≤ 0.36). Two binary phases extend into the ternary system forming solid solutions, i.e. Sr 14 Cu 24-x Co x O 41-δ (0 ≤ x ≤ 5) and Sr 6+x Co 5-y Cu y O 15+δ (0 ≤ x ≤ 0.36, 0 ≤ y ≤ 1.0). The Sr 6+x Co 5 O 15+δ solid solution was found to undergo a phase separation into a mixture of Sr 6 Co 5 O 15-δ and Sr 14 Co 11 O 33 upon annealing at 600°C. This transformation is reversible.

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Subsolidus Phase Relations of the SrO-In2O3-CuO System in Air

Cited by 4 publications

References 37 publications

Phase Relations in Ternary Systems in the Subsolidus Region: Methods To Formulate Solid Solution Equations and To Find Particular Compositions

Phase Relations in Ternary Systems in the Subsolidus Region: Methods To Formulate Solid Solution Equations and To Find Particular Compositions

Subsolidus Phase Relations of the CaO-REOx -CuO Systems (RE = Eu, Tb, Dy, Ho, Er, Lu and Sc) at 900 °C in Air

Subsolidus Phase Relations of the CoOx-CuO-SrO System

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