“…The synthetic linkage of triphenylamines (TPA), indolocarbazole (ICz) as well as phenylcarbazole (PCz) scaffolds and thiophene‐based linkers toward symmetrical bis(triarylamines) was realized by Suzuki cross‐coupling reaction. A general procedure developed in an earlier study tolerating a broad spectrum of functionalized TPA boronic acid esters was applied for the synthesis of BoMA‐1T , BHA‐2T , BpMA‐2T , BMOA‐2T , BFA‐2T , BoMA‐2T , PCz‐2T , ICz‐2T , BHA‐3T , BpMA‐3T , BMOA‐3T , BFA‐3T , BHA‐4T , BpMA‐4T , BMOA‐4T , BFA‐4T , BHA‐TT , BoMA‐TT , PCz‐TT , ICz‐TT , BHA‐DTT , BoMA‐DTT , PCz‐DTT , ICz‐DTT , PCz‐1T and ICz‐1T . A convenient synthetic pathway for planarized TPA moieties PCz and ICz was previously described .…”