Sulfonated magnetic carbon nanoparticles from eucalyptus oil as a green and sustainable catalyst for converting fructose to 5-HMF

Le, Giang T.T.; Arunaditya, Kantapong; Panichpol, Jamekorn; Rodruangnon, Tanapat; Thongratkaew, Sutarat; Chaipojjana, Kawisa; Faungnawakij, Kajornsak; Charinpanitkul, Tawatchai

doi:10.1016/j.catcom.2020.106229

Cited by 19 publications

(6 citation statements)

References 28 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…DES MA/Gly/B was a better catalyst for efficient catalysis of d -fructose to 5-HMF compared to ChCl/oxalic acid (OA), MeSAPO-11, cetyltrimethyl ammonium bromide (CTAB)/Al 2 O 3 , Si-3-IL-HSO 4 , and sulfonated magnetic carbon nanoparticle (SMCN) (Table ). − …”

Section: Results and Discussionmentioning

confidence: 99%

Biocatalytic Valorization of Biobased 5-Hydroxymethylfurfural to 5-Hydroxymethyl-2-furfurylamine in a Three-Constituent Deep Eutectic Solvent–Water System

Wang

Chai

Ren

et al. 2022

ACS Sustainable Chem. Eng.

View full text Add to dashboard Cite

5-Hydroxymethyl-2-furfurylamine (HMFA), as an important 5-hydroxymethylfurfural (5-HMF) derivative, has many potential applications in the preparation of diuretics, antihypertensive drugs, preservatives, and curing agents. In this work, highly efficient valorization of biomass-derived D-fructose into HMFA was attempted via a cascade reaction in a three-constituent deep eutectic solvent (3c-DES)−H 2 O. Using D-fructose (63.0 g/L) as a raw material, the yield of 5-HMF reached 68.2% in 3c-DES malic acid/glycerol/betaine−H 2 O (9:91, wt/wt) (pH 2.3) at 170 °C in 30 min. Whole cells of Escherichia coli CV harboring transaminase were utilized to valorize biomass-derived 5-HMF to HMFA at pH 8.0 and 30 °C using amine donor L-alanine. The valorization of 600 mM commercial 5-HMF gave a 93.2% yield of HMFA with 99.2% selectivity. In addition, CV cells transformed D-fructosevalorized 5-HMF into HMFA in 94.1% yield in 3c-DES malic acid/glycerol/betaine−H 2 O. This approach provided a sustainable and eco-efficient idea for chemoenzymatically valorizing biomass-derived D-fructose to HMFA.

show abstract

Section: Results and Discussionmentioning

confidence: 99%

Biocatalytic Valorization of Biobased 5-Hydroxymethylfurfural to 5-Hydroxymethyl-2-furfurylamine in a Three-Constituent Deep Eutectic Solvent–Water System

Wang

Chai

Ren

et al. 2022

ACS Sustainable Chem. Eng.

View full text Add to dashboard Cite

show abstract

“…31,32 Sulfonated magnetic carbon nanoparticles provided an HMF yield of 51.6% at 84% fructose conversion, a temperature of 180 °C, and a reaction time of 30 min, using H 2 O as a solvent. 33 The HMF yield obtained through carbon catalysts can be improved by introducing microwave irradiation. Carbon materials are excellent absorbers of microwaves.…”

Section: 2mentioning

confidence: 99%

“…The high cost of the catalyst can be overcome by using low-cost, less-expensive carbon core-based solid catalysts. Apart from being inexpensive, the carbon-based solid catalysts with a carbon core are more porous, have low density, high surface area, and are easily recyclable. , Sulfonated magnetic carbon nanoparticles provided an HMF yield of 51.6% at 84% fructose conversion, a temperature of 180 °C, and a reaction time of 30 min, using H 2 O as a solvent . The HMF yield obtained through carbon catalysts can be improved by introducing microwave irradiation.…”

Section: Hmf Synthesis From Sugarsmentioning

confidence: 99%

A Review on Green and Efficient Synthesis of 5-Hydroxymethylfurfural (HMF) and 2,5-Furandicarboxylic Acid (FDCA) from Sustainable Biomass

Aranha

Gogate

2023

Ind. Eng. Chem. Res.

View full text Add to dashboard Cite

The present work gives an overview of the approaches for green synthesis of 5-hydroxymethylfurfural (HMF) and 2,5 furan dicarboxylic acid (FDCA) focusing on reduction in the byproduct formation such as levulinic acid and humins. It was elucidated that the use of highly polar and aqueous solvents, high Brønsted acidity, high pH, reaction time, and temperature increases the levulinic acid formation in the reaction. In contrast, humin formation is increased by high basicity, temperature, and initial substrate concentration. Specific catalytic and solvent systems for minimizing the byproduct formation during HMF synthesis are also discussed along with options for use of microwave, ultrasound, and continuous processes. In terms of intensification, safety, and ease of scale-up, the use of ultrasound for HMF synthesis is promising; however, microreactors are currently a better choice for higher substrate concentration usage and higher yields. Effect of parameters like reaction time, temperature, oxidizing source, solvent, and base on FDCA synthesis is also analyzed. Depending on the reaction conditions and the reactor type, the optimum temperature typically should be between 80 and 160 °C, moderate bases, such as K2CO3 and KHCO3, are preferred to maintain a preferred pH of 7−11 and O2 is an ideal oxidizing agent. The reaction pathway for FDCA synthesis from HMF was also studied and the effect of the base and solvent elucidated. Finally, one-pot synthesis of FDCA from HMF and the strategies necessary to optimize the FDCA yield has been discussed. It was demonstrated that one-pot two-step FDCA synthesis from sugars provides enhanced FDCA yield, selectivity, and lower byproduct formation, compared to one-pot one-step synthesis.

show abstract

“…At 170 °C/3 h, 92% xylose conversion and 57% FF yield were achieved in the MIBK/H 2 O biphasic solvent system. Le et al 77 synthesized magnetic carbon nanoparticles by copyrolysis of eucalyptus oil and ferrocene. Then the heterogeneous catalyst was prepared by -SO 3 H grafting, resulting in a decrease of the amorphous structure and increase of the specific surface area.…”

Section: Development and Classification Of Carbon-based Solid Acidsmentioning

confidence: 99%

Critical Review on the Preparation of Platform Compounds from Biomass or Saccharides via Hydrothermal Conversion over Carbon-Based Solid Acid Catalysts

et al. 2021

View full text Add to dashboard Cite

The use of carbon-based catalysts to catalyze the hydrothermal conversion of biomass and its derived carbohydrates to produce platform compounds such as 5-(hydroxymethyl)furfural (HMF), levulinic acid (LA), and furfural (FF) has a long history. The excellent thermal stability and chemical activity and low preparation cost of carbon-based catalysts make them develop rapidly in catalytic hydrothermal conversion, which is the core attention in the review. Carbon catalysts are divided into sulfuric acid-based carbon catalysts, phosphoric acid-based carbon catalysts, metal-supported carbon catalysts and other types of carbon catalysts, to study their application to hydrothermal decomposition of monosaccharides, disaccharides, polysaccharides, and biomass. The characteristics of different types of carbon catalysts were introduced. The diversified development of carbon-based catalysts and the upgrading of feedstocks have promoted the improvement of product selectivity, cost, and energy optimization, realizing the transformation of hydrothermal decomposition of biomass into a greener process. However, the development of efficient catalytic systems for hydrothermal conversion of abundant, cheap, and readily available biomass sources is still an ideal choice to expand the process strategy.

show abstract

Sulfonated magnetic carbon nanoparticles from eucalyptus oil as a green and sustainable catalyst for converting fructose to 5-HMF

Cited by 19 publications

References 28 publications

Biocatalytic Valorization of Biobased 5-Hydroxymethylfurfural to 5-Hydroxymethyl-2-furfurylamine in a Three-Constituent Deep Eutectic Solvent–Water System

Biocatalytic Valorization of Biobased 5-Hydroxymethylfurfural to 5-Hydroxymethyl-2-furfurylamine in a Three-Constituent Deep Eutectic Solvent–Water System

A Review on Green and Efficient Synthesis of 5-Hydroxymethylfurfural (HMF) and 2,5-Furandicarboxylic Acid (FDCA) from Sustainable Biomass

Critical Review on the Preparation of Platform Compounds from Biomass or Saccharides via Hydrothermal Conversion over Carbon-Based Solid Acid Catalysts

Contact Info

Product

Resources

About