Supramolecular polynuclear clusters sustained cubic hydrogen bonded frameworks with octahedral cages for reversible photochromism
Xiaojun Ding,
Jing Chen,
Gang Ye
Abstract:Developing supramolecular porous crystalline frameworks with tailor-made architectures from advanced secondary building units (SBUs) remains a pivotal challenge in reticular chemistry. Particularly for hydrogen-bonded organic frameworks (HOFs), construction of geometrical cavities through secondary units has been rarely achieved. Herein, a body-centered cubic HOF (TCA_NH4) with octahedral cages was constructed by a C3-symmetric building block and NH4+ node-assembled cluster (NH4)4(COOH)8(H2O)2 that served as s… Show more
“…As a multifunctional luminescent framework material with both luminescent and porosity properties, it has a broad application prospect in the field of sensing. 63,68,72,94–102…”
Section: Diverse Applications For Flexible Hofsmentioning
Flexible behavior is one of the most fascinating features of hydrogen-bonded organic frameworks (HOFs), which represent an emerging class of porous materials that were self-assembled via H-bonding between organic building...
“…As a multifunctional luminescent framework material with both luminescent and porosity properties, it has a broad application prospect in the field of sensing. 63,68,72,94–102…”
Section: Diverse Applications For Flexible Hofsmentioning
Flexible behavior is one of the most fascinating features of hydrogen-bonded organic frameworks (HOFs), which represent an emerging class of porous materials that were self-assembled via H-bonding between organic building...
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