Surface composition of BaTiO3/SrTiO3(001) films grown by atomic oxygen plasma assisted molecular beam epitaxy

Abstract

International audienceWe have investigated the growth of BaTiO3 thin films deposited on pure and 1% Nb-doped SrTiO3(001) single crystals using atomic oxygen assisted molecular beam epitaxy and dedicated Ba and Ti Knudsen cells. Thicknesses up to 30nm were investigated for various layer compositions. We demonstrate 2D growth and epitaxial single crystalline BaTiO3 layers up to 10nm before additional 3D features appear; lattice parameter relaxation occurs during the first few nanometers and is completed at similar to 10 nm. The presence of a Ba oxide rich top layer that probably favors 2D growth is evidenced for well crystallized layers. We show that the Ba oxide rich top layer can be removed by chemical etching. The present work stresses the importance of stoichiometry and surface composition of BaTiO3 layers, especially in view of their integration in devices. (C) 2012 American Institute of Physics. [http://dx.doi.org/10.1063/1.4768469

Determination of the cation site distribution of the spinel in multiferroic CoFe 2 O 4 /BaTiO 3 layers by X-ray photoelectron spectroscopy

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Manipulating the ferroelectric polarization state of BaTiO3 thin films

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