“…Geochemical tracers including major ions, stable isotopes and radiogenic isotopes have been used to estimate groundwater fluxes in gaining rivers (Cartwright et al, 2008(Cartwright et al, , 2010Cook, 2012;Cook et al, 2003Cook et al, , 2006Durand et al, 1993;Genereux et al, 1993;Genereux and Hemond, 1990;Lamontagne et al, 2005Lamontagne et al, , 2008Lamontagne and Cook, 2007;Mullinger et al, 2007Mullinger et al, , 2009Négrel et al, 2003;Rhode, 1981;Ribolzi et al, 2000;Stellato et al, 2008). The utility of each of these tracers depends on a variety of factors including the difference between the concentration of the tracer in groundwater compared to surface water, its spatial and temporal variability, the accurate characterisation of its sources and sinks, and the potential for it to change by processes such as evaporation, precipitation, radioactive decay, degassing, or biogeochemical reactions.…”