Synergistic toxicity between glyphosate and 2,4-dinitrophenol on budding yeast is not due to H&lt;sub&gt;2&lt;/sub&gt;O&lt;sub&gt;2&lt;/sub&gt;-mediated oxidative stress

Daviere, Antoine; Sotomski, Maximilien; Audibert, Agnès; Carol, Pierre; Hubert, Steve; Lebreton, Sandrine; Louvet-Vallée, Sophie; Pédron, Jacques; Puyaubert, Juliette; Kraepiel, Yvan; Lacoste, Jérôme

doi:10.19185/matters.201903000030

Cited by 1 publication

(1 citation statement)

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“…Therefore, secondary environmental nitrophenols might in principle arise from a plethora of nitration pathways, of which photonitration is only one of the possibilities. In contrast, it is quite difficult to account for the nitration of nitrophenols (2NP, 4NP) to 2,4-dinitrophenol (24DNP), i.e., the most phytotoxic nitrophenol compound [ 56 , 57 ], without invoking the photoinduced nitration pathways.…”

Section: Aromatic Photonitration In Aqueous Solutionmentioning

confidence: 99%

Secondary Formation of Aromatic Nitroderivatives of Environmental Concern: Photonitration Processes Triggered by the Photolysis of Nitrate and Nitrite Ions in Aqueous Solution

Marussi

Vione

2021

Molecules

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Aromatic nitroderivatives are compounds of considerable environmental concern, because some of them are phytotoxic (especially the nitrophenols, and particularly 2,4-dinitrophenol), others are mutagenic and potentially carcinogenic (e.g., the nitroderivatives of polycyclic aromatic hydrocarbons, such as 1-nitropyrene), and all of them absorb sunlight as components of the brown carbon. The latter has the potential to affect the climatic feedback of atmospheric aerosols. Most nitroderivatives are secondarily formed in the environment and, among their possible formation processes, photonitration upon irradiation of nitrate or nitrite is an important pathway that has periodically gained considerable attention. However, photonitration triggered by nitrate and nitrite is a very complex process, because the two ionic species under irradiation produce a wide range of nitrating agents (such as •NO2, HNO2, HOONO, and H2OONO+), which are affected by pH and the presence of organic compounds and, in turn, deeply affect the nitration of aromatic precursors. Moreover, aromatic substrates can highly differ in their reactivity towards the various photogenerated species, thereby providing different behaviours towards photonitration. Despite the high complexity, it is possible to rationalise the different photonitration pathways in a coherent framework. In this context, this review paper has the goal of providing the reader with a guide on what to expect from the photonitration process under different conditions, how to study it, and how to determine which pathway(s) are prevailing in the formation of the observed nitroderivatives.

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Section: Aromatic Photonitration In Aqueous Solutionmentioning

confidence: 99%