Synthese und reaktivität von silicium-übergangsmetallkomplexen. XXIX. Trihydridosilyl-komplexe von eisen und ruthenium: Ein einfacher Zugang, ligandaustauschreaktionen am metall und schwingungsspektroskopische analyse

Reactions of Hydrosilanes with Transition-Metal Complexes: Formation of Stable Transition-Metal Silyl Compounds

“…Structural data reported for silyl−transition-metal complexes prepared from hydrosilanes and that include only those derivatives with “classical” M−Si, M−H, and/or Si−H bonds are summarized in Table . − …”

“…Si(Fe,Ru,Os) bonds prepared by other methods or preceding 1980 and structurally characterized. SiFe: 2.218(2); 2.222(3); , 2.224(1); 2.2277(14); 2.230(2); 2.2330(14); 2.249(1); , 2.249(3); 2.252(3); 2.258(1); 2.260(6); 2.262(2); , 2.262(1); 2.263(1); 2.263(2), 2.264(2); 2.264(2); 2.265(1); 2.266(3); 2.267(1); 2.268(8); 2.271(4); 2.275(2); 2.278(1); 2.280(3); 2.281(4); 2.285(3); 2.286(5); 2.286(1); 2.287(2); 2.290(3); 2.294(1); 2.296(2); 2.297(3); 2.301(1); 2.303(1); 2.307(1); 2.307(2); 2.310(1); 2.322(1); 2.311(2); 2.311(3); 2.3l3(6); 2.315(2); 2.316(13); 2.322(4); 2.325(3); 2.326(3); 2.327(3); 2.328(1); 2.33(1); 2.330(2); 2.338(4); 2.339(2); 2.339(1); 2.341(2); 2.346; 2.347(1); 2.350(1); 2.354(2); 2.356; 2.356(1); 2.357(3); , 2.364(5); 2.365(2); 2.366(2); 2.366(1); 2.375(2); 2.378(1);…”

Structural characterization of the anionic halfsandwich complex and its reactivity towards stannanes and distannanes

“…The outstanding preparative versatility of this route has led to a vast range of organometallic species so far, most of which have been obtained from group 13 [4][5][6][7][8][9][10][11][12][13][14][15] and group 14 precursors [16][17][18][19][20].…”

Ruthenium Silyl Complexes Containing the Cp(PMe3)2Ru Moiety: Preparation, Substituent Effects, and Silylene Character in the Ru−Si Bond

“…Malisch and co-workers successfully prepared a wide variety of late transition metal silyl complexes of the type L n MSiX 3 (ML n = CpCr(CO) 3 , CpMo(CO) 3 , Cp*Mo(CO) 3 , CpMo(CO) 2 (PMe 3 ), Cp*Mo(CO) 2 (PMe 3 ), CpW(CO) 3 , Cp*W(CO) 3 , CpW(CO) 2 (PMe 3 ), Cp*W(CO) 2 (PMe 3 ), CpFe(CO) 2 , Cp*Fe(CO) 2 , CpRu(CO) 2 , Cp*Ru(CO) 2 ; SiX 3 = SiHCl 2 , SiHMeCl, SiHMe 2 , SiPhHCl, SiPh 2 H, etc.) by reacting metal anions with the corresponding chlorosilane in hydrocarbon solvent. − Controlled exchange reactions at silicon afforded a variety of metallohydrosilanes, − -fluorosilanes, -aminosilanes, , -silanols, ,− and -alkoxysilanes…”