Syntheses, crystal structures and fluorescent properties of R,R-DIOP based copper (I) and cadmium (II) complexes {R,R-DIOP = (4R,5R)-trans-4,5-bis(diphenylphosphinomethyl)-2,2-dimethyl-1,3-dioxalane}

Li, Jun‐Xia; Du, Zongliang; An, Huiqin; Zhou, Jian; Dong, Jun; Wang, Shurong; Zhu, Baolin; Zhang, Shoumin; Wu, Shuai; Huang, Wei‐Ping

doi:10.1016/j.molstruc.2009.07.006

Cited by 8 publications

(1 citation statement)

References 47 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…There are mononuclear structures with mono-and bi-functional phosphane ligands, as exemplified by CdCl 2 (PPh 3 ) 2 [6] and CdCl 2 (dppf) [7], respectively; dppf is 1,1′-bis(diphenylphosphanyl) ferrocene. Prior to the most recent study [5], the only other polymeric structure was that formed between CdCl 2 and (R,R)-trans-4,5-bis(diphenylphosphinomethyl)-2,2-dimethyl-1,3-dioxalane [8]. The title one-dimensional coordination polymer [CdCl 2 (dppp)]n, (I), where dppp is 1,5-bis (diphenylphosphino)propane, was determined in continuation of on-going studies of cadmium coordination polymers [5,[9][10][11].…”

Section: Commentmentioning

confidence: 99%

Crystal structure of catena-poly[{μ₂-1,5-bis(diphenylphosphanyl)pentane-κ² P:P′}dichloridocadmium(II)], C₂₉H₃₀CdCl₂P₂

Tan

Tiekink

2019

Zeitschrift Für Kristallographie - New Crystal Structures

View full text Add to dashboard Cite

show abstract

Section: Commentmentioning

confidence: 99%

Crystal structure of catena-poly[{μ₂-1,5-bis(diphenylphosphanyl)pentane-κ² P:P′}dichloridocadmium(II)], C₂₉H₃₀CdCl₂P₂

Tan

Tiekink

2019

Zeitschrift Für Kristallographie - New Crystal Structures

View full text Add to dashboard Cite

show abstract

Synthesis of Chiral Tertiary α,α‐Difluoromethyl Carbinols by Cu‐Catalyzed Asymmetric Propargylation

Guo

Zhang

Wang

et al. 2019

Chemistry A European J

View full text Add to dashboard Cite

Chiral a,a-difluoromethyl carbinolsa re recurring structural motifs in many therapeutic agents. Despite the indubitable interesti nt he catalytic asymmetric synthesis of such compounds,t his research field still remains largely underexplored. Herein, an efficient approacht oarange of chiral homopropargylic a,a-difluoromethyl carbinols has been developed, through aC u-catalyzed enantioselective propargylation of a,a-difluoroketones with (pinacolato)allenylboron. In the presence of ac uprous complex, generated in situ from CuCl and as piroketal-based diphosphine( SKP) ligand, av ariety of aryl-, heteroaryl-, alkyl-, alkynyl,a lkenyl, or benzyloxycarbonyl-substituted a,a-difluoromethyl carbinols were obtained in 75-99 %y ields with 84-98 % ee values. The catalytic system was further investigated using a combined dynamic NMR spectroscopic,X -ray crystallographic, and non-linear effect studies. The origin of the enantioselectivity was rationalized based on DFT calculations.F inally, several efficient transformations were showcased to highlight the utilities of the protocol in synthesis of complex compounds bearing an a,a-difluoromethyl carbinol moiety.[a] Dr.Supporting information and the ORCID identification number(s) for the author(s) of this articlecan be found under: https://doi.

show abstract

Synthetic protocols and applications of copper(I) phosphine and copper(I) phosphine/diimine complexes

Babgi

2021

Journal of Organometallic Chemistry

View full text Add to dashboard Cite

Syntheses, crystal structures and fluorescent properties of R,R-DIOP based copper (I) and cadmium (II) complexes {R,R-DIOP = (4R,5R)-trans-4,5-bis(diphenylphosphinomethyl)-2,2-dimethyl-1,3-dioxalane}

Cited by 8 publications

References 47 publications

Crystal structure of catena-poly[{μ₂-1,5-bis(diphenylphosphanyl)pentane-κ² P:P′}dichloridocadmium(II)], C₂₉H₃₀CdCl₂P₂

Crystal structure of catena-poly[{μ₂-1,5-bis(diphenylphosphanyl)pentane-κ² P:P′}dichloridocadmium(II)], C₂₉H₃₀CdCl₂P₂

Synthesis of Chiral Tertiary α,α‐Difluoromethyl Carbinols by Cu‐Catalyzed Asymmetric Propargylation

Synthetic protocols and applications of copper(I) phosphine and copper(I) phosphine/diimine complexes

Contact Info

Product

Resources

About

Syntheses, crystal structures and fluorescent properties of R,R-DIOP based copper (I) and cadmium (II) complexes {R,R-DIOP = (4R,5R)-trans-4,5-bis(diphenylphosphinomethyl)-2,2-dimethyl-1,3-dioxalane}

Cited by 8 publications

References 47 publications

Crystal structure of catena-poly[{μ2-1,5-bis(diphenylphosphanyl)pentane-κ2 P:P′}dichloridocadmium(II)], C29H30CdCl2P2

Crystal structure of catena-poly[{μ2-1,5-bis(diphenylphosphanyl)pentane-κ2 P:P′}dichloridocadmium(II)], C29H30CdCl2P2

Synthesis of Chiral Tertiary α,α‐Difluoromethyl Carbinols by Cu‐Catalyzed Asymmetric Propargylation

Synthetic protocols and applications of copper(I) phosphine and copper(I) phosphine/diimine complexes

Contact Info

Product

Resources

About

Crystal structure of catena-poly[{μ₂-1,5-bis(diphenylphosphanyl)pentane-κ² P:P′}dichloridocadmium(II)], C₂₉H₃₀CdCl₂P₂

Crystal structure of catena-poly[{μ₂-1,5-bis(diphenylphosphanyl)pentane-κ² P:P′}dichloridocadmium(II)], C₂₉H₃₀CdCl₂P₂