Syntheses, crystal structures and magnetic property of two azido-bridged coordination polymers with 1,2-diaminocyclohexane as co-ligand

Syntheses and topological networks of two azide complexes based on 4-amino-3,5-bis(3-pyridyl)-1,2,4-triazole ligands

“…This versatile ligand can act as a monodentate ligand as well as bridging ligand adopting the end-on (EO) or endto-end (EE) modes. A huge number of complexes with various structures have been obtained by introducing co-bridging ligands to the metal-azide system [5,6]. While 1,2,4-triazole and its derivatives are also good candidates for the construction of various metal coordination polymers [7][8][9][10].…”

“…It is mainly depended on the geometry of the ligands and central metal ions [16]. Particular attention has been attracted to the 2D topologies that contain three-, four-, or six-sided polygons with the features as (3,6), (4,4) and (6,3) nets and so on [17][18][19]. However, the networks that consist of mixed nodes in 2D arrangement are rarely observed.…”

A Novel Copper Complex with Multibridging Coordination Mode: Synthesis, Structure, Luminescent and Magnetic Properties

“…As we know copper is a very attractive framework candidate to construct functional materials because of its capability to coordinate with unsaturated N-, O-atoms. So far, a great number of MOFs containing copper atoms and carboxylicate group have been prepared, however, most of which display single property, either optical or magnetic property alone [11][12][13][14], so it is still a challenge to construct metal complexes with multi-functionality, e.g., magnetic and optical properties [15]. An attractive approach to obtain multi-functional materials might be design multifunctional organic ligand as building block.…”