Syntheses, structures, and optical limiting capability of tetranuclear cubane, hexanuclear prism-cage, and octanuclear double-cubane argento-selenotungstates

Wang, Zhimin; Shen, Su-Mei; Shen, Xiao; Shi, Hua‐Tian; Jia, Ai‐Quan; Zhang, Qian‐Feng

doi:10.1016/j.poly.2016.01.036

Polyhedron

2016

DOI: 10.1016/j.poly.2016.01.036

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Syntheses, structures, and optical limiting capability of tetranuclear cubane, hexanuclear prism-cage, and octanuclear double-cubane argento-selenotungstates

Zhimin Wang

Su-Mei Shen

Xiao Shen

et al.

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2024

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Synthesis, structure and optically limiting NLO properties of a distorted cubane-like cluster (µ-Cl)(µ ₃-WSe₄)(CuPPh₃)₃

Chen,

Liang,

Pan

et al. 2024

Zeitschrift Für Naturforschung B

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Treatment of [Et4N]2[WSe4] with three equivalents of CuCl and PPh3 (Ph = phenyl) in a mixed solvent of 25 mL of CH2Cl2 and 5 mL of DMF afforded a distorted cubane-like cluster [(µ-Cl)(µ 3-WSe4)(CuPPh3)3] (1), which has been structurally characterized by single-crystal X-ray diffraction. The coordination geometry of the tungsten center and two copper atoms is tetrahedral, whereas that of the other copper atom is triangular. Regarding the NLO properties, a large optical limiting effect with a threshold of 0.91 J cm−2 was observed with laser pulses of 7 ns at 532 nm.

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Synthesis, structure and optically limiting NLO properties of a distorted cubane-like cluster (µ-Cl)(µ ₃-WSe₄)(CuPPh₃)₃

Chen,

Liang,

Pan

et al. 2024

Zeitschrift Für Naturforschung B

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Syntheses, structures, and optical limiting capability of tetranuclear cubane, hexanuclear prism-cage, and octanuclear double-cubane argento-selenotungstates

Cited by 1 publication

References 50 publications

Synthesis, structure and optically limiting NLO properties of a distorted cubane-like cluster (µ-Cl)(µ ₃-WSe₄)(CuPPh₃)₃

Synthesis, structure and optically limiting NLO properties of a distorted cubane-like cluster (µ-Cl)(µ ₃-WSe₄)(CuPPh₃)₃

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Syntheses, structures, and optical limiting capability of tetranuclear cubane, hexanuclear prism-cage, and octanuclear double-cubane argento-selenotungstates

Cited by 1 publication

References 50 publications

Synthesis, structure and optically limiting NLO properties of a distorted cubane-like cluster (µ-Cl)(µ 3-WSe4)(CuPPh3)3

Synthesis, structure and optically limiting NLO properties of a distorted cubane-like cluster (µ-Cl)(µ 3-WSe4)(CuPPh3)3

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Synthesis, structure and optically limiting NLO properties of a distorted cubane-like cluster (µ-Cl)(µ ₃-WSe₄)(CuPPh₃)₃

Synthesis, structure and optically limiting NLO properties of a distorted cubane-like cluster (µ-Cl)(µ ₃-WSe₄)(CuPPh₃)₃