Synthesis and characterization of 2,7-dihydro-1H-dinaphtho[c,e]tellurepin: a new heterocyclic telluride

Al‐Rubaie, Ali Z.; Fahad, Tarik A; Al-Jadaan, Shaker A. N.; Aboud, Naji A

doi:10.1016/j.jorganchem.2004.04.028

Cited by 11 publications

(10 citation statements)

References 18 publications

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“…Single concentration data (10 −3 M) are shown in the "Experimental" section. The values of molar conductance approach those expected for 1:1 electrolytes [3,4,6,8]. Compounds 11, 12, 13, and 14 have low conductivities.…”

Section: Resultssupporting

confidence: 68%

“…The mixture was refluxed under nitrogen atmosphere for 3 h, giving a pale yellow solution of Na 2 Te. To the resulting yellow solution was added a deaerated solution of bromomethylcyclohexane (11.68 g; 66 mmol) in 150 cm 3 of methanol. The solution was refluxed for 5 h, and then cooled to room temperature.…”

Section: Di(cyclohexylmethyl)telluride (1)mentioning

confidence: 99%

“…The solution was refluxed for 5 h, and then cooled to room temperature. The solution was filtered hot, cooled to room temperature, and extracted with diethyl ether (3 × 100 cm 3 ). The combined extracts were dried with anhydrous MgSO 4 .…”

Section: Di(cyclohexylmethyl)telluride (1)mentioning

confidence: 99%

“…Telluronium salts of type Ph 2 Te(CH 3 )X (where X = Cl, Br, I, NCS, PhCOO) reductively eliminate CH 3 X in solvents such as chloroform and DMF.…”

Section: Introductionmentioning

confidence: 99%

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Synthesis, characterization, and solution properties of some new organotellurium compounds based on di(cyclohexylmethyl)telluride

Al‐Rubaie

Al-Derawi

2007

Heteroatom Chemistry

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Section: Resultssupporting

confidence: 68%

Section: Di(cyclohexylmethyl)telluride (1)mentioning

confidence: 99%

Section: Di(cyclohexylmethyl)telluride (1)mentioning

confidence: 99%

“…Telluronium salts of type Ph 2 Te(CH 3 )X (where X = Cl, Br, I, NCS, PhCOO) reductively eliminate CH 3 X in solvents such as chloroform and DMF.…”

Section: Introductionmentioning

confidence: 99%

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Synthesis, characterization, and solution properties of some new organotellurium compounds based on di(cyclohexylmethyl)telluride

Al‐Rubaie

Al-Derawi

2007

Heteroatom Chemistry

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“…[1][2][3][4] Some years ago, we demonstrated the use of potassium tellurocyanates in preparing various cyclic tellurides [5][6][7] and new phenacyl derivatives of tellurium. 8 Furthermore, the reaction of potassium tellurocyanate with hydrazidoyl bromide in DMSO solution afforded 2,4-disubsituted-4-imino-2 -1,3,4-telluradiazolines together with α-tellurocyantobenzaldehyde arylhydrazone.…”

Section: Introductionmentioning

confidence: 99%

Potassium Tellurocyanate Mediated Coupling Reactions ofN-(1-Chloroethylidene)Arylamines

Al-Jadaan

Al-Masoudi

Saeed

et al. 2014

Phosphorus, Sulfur, and Silicon and the Related Elements

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The reaction of potassium tellurocyanate Cl, CH 3 and NO 2 ) in DMSO solution gave unexpectedly, after hydrolysis, the corresponding N-(3-(arylamino)butan-2-ylidene)arylamines in 63-78%. Reaction of N-(3-(arylamino)butan-2-ylidene)arylamines with SOCl 2 or with Br 2 resulted in the substitution of a halogen on the aromatic rings. The presence of a water molecule within the structure of the synthesized diimines was rationalized theoretically by Density Functional Theory (DFT). All compounds were characterized by elemental analysis, IR, NMR and mass spectroscopic data.

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A Summary of Functional Groups Containing Selenium and Tellurium: A Catalog of the Many Groups that are Known and Some that are Not

Hack

Liebman

2013

Patai's Chemistry of Functional Groups

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In the current chapter we provide a catalog of functional groups containing the chalcogens selenium and tellurium where by functional group we mean the central atom, Se or Te, and its local arrangement of atoms bonded to it by single or multiple bonds (its neighborhood). We will do so by cataloging examples of compounds containing the groups. The atoms that define the local neighborhood are limited here to H, C, N, the chalcogens O, S, Se, Te, and the halogens F, Cl, Br and I. As such we avoid Se‐ and Te‐bonding to metals and metalloids and so we will ignore all salts, and we also ignore all groups with formal charges. However arbitrarily, we did include complexes involving species wherein, with appropriate bond‐shifting, we can draw the compound of interest without any formal charges. We have also avoided mention of free radicals and other species with unpaired electrons. All of the groups were explicitly chosen, and have at least one carbon attached to the selenium or tellurium. For each group we generally give one compound as an example (admittedly our choice of name is often unsystematic), a reference to the primary literature (again chosen unsystematically), and the CAS RN for the example compound (when available). Where there is no example we will generally explicitly say so, occasionally with due annotation as NO CAS RN or “no compounds identified” to encourage their study.

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Synthesis and characterization of 2,7-dihydro-1H-dinaphtho[c,e]tellurepin: a new heterocyclic telluride

Cited by 11 publications

References 18 publications

Synthesis, characterization, and solution properties of some new organotellurium compounds based on di(cyclohexylmethyl)telluride

Synthesis, characterization, and solution properties of some new organotellurium compounds based on di(cyclohexylmethyl)telluride

Potassium Tellurocyanate Mediated Coupling Reactions ofN-(1-Chloroethylidene)Arylamines

A Summary of Functional Groups Containing Selenium and Tellurium: A Catalog of the Many Groups that are Known and Some that are Not

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