Synthesis and characterization of a zinc metal–organic framework with chiral nano-pores

Dynamic Zn-based metal–organic framework: stepwise adsorption, hysteretic desorption and selective carbon dioxide uptake

“…The structure of 1 is arranged in a helical fashion about these axes, which are the source of the chirality of the microporous framework, and a similar network has been obtained in a recent report. 11 Moreover, such an arrangement makes the framework of 1 become a 3D continuous intersecting channel system (Fig. 2 and S3 †) with highly solvent accessible voids of 57.7%.…”

Zn‐MOFs Containing Pyridine and Bi­pyridine Carboxylate Organic Linkers and Open Zn2+ Sites

“… XRD patterns of ZnMOF‐BPDC: as‐synthesized (black), thermal drying (red), Sc CO 2 drying (green), and simulated (blue). Simulated XRD patterns of Zn 3 (BPDC) 2 (O 2 CH) 2 (DEF) 2 (magenta)12a and Zn(BPDC)(H 2 O) 2 (maroon) 12b…”

Breathing 3D Frameworks with T-Shaped Connecting Ligand Exhibiting Solvent Induction, Metal Ions Effect and Luminescent Properties

“…The multidentate ligand 2,2 -bipyridine-5,5 -dicarboxylic acid (H 2 bpdc) is a good candidate because it contains two types of coordination groups-carboxylate groups and chelating position N-donors-which can act in linear bridging mode and/or T-shaped connecting mode [20][21][22][23][24][25][26][27][28][29][30][31][32][33][34][35][36][37]. To date, there are 20 different coordination modes for H 2 bpdc ligand observed in the structures retrieved from the Cambridge Structural Database (CSD version 5.38, February 2017) [38] (Figure 1, Scheme S1).…”