Synthesis and characterization of bio‐based poly(ethylene 2,5‐furandicarboxylate)‐b‐poly(butylene adipate‐co‐terephthalate) copolymers

Zhang, Wei; Wang, Qingyin; Wang, Gongying; Liu, Shaoying

doi:10.1002/app.52803

Cited by 3 publications

(2 citation statements)

References 44 publications

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“…Rodenburg was also reported as a manufacturer of PBAT in the past [82]. The FDCA analog PBAF is also under development [127,128].…”

Section: Phasmentioning

confidence: 99%

A Review on Melt-Spun Biodegradable Fibers

Naeimirad,

Krins,

Gruter

2023

Sustainability

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The growing awareness of environmental issues and the pursuit of sustainable materials have sparked a substantial surge in research focused on biodegradable materials, including fibers. Within a spectrum of fabrication techniques, melt-spinning has emerged as an eco-friendly and scalable method for making fibers from biodegradable plastics (preferably bio-based), intended for various applications. This paper provides a comprehensive overview of the advancements in the realm of melt-spun biodegradable fibers. It delves into global concerns related to micro- and nanoplastics (MNPs) and introduces the concept of biodegradable fibers. The literature review on melt-spun biodegradable monofilaments and multifilaments unveils a diverse range of polymers and copolymers that have been subjected to testing and characterization for their processing capabilities and the performance of the resultant fibers, particularly from mechanical, thermal, and biodegradation perspectives. The paper discusses the impact of different factors such as polymer structure, processing parameters, and environmental conditions on the ultimate properties, encompassing spinnability, mechanical and thermal performance, and biodegradation, with schematic correlations provided. Additionally, the manuscript touches upon applications in sectors such as clothing, technical textiles, agriculture, biomedical applications, and environmental remediation. It also spotlights the challenges encountered in the commercialization of these fibers, addresses potential solutions, and outlines future prospects. Finally, by shedding light on the latest developments, challenges, and opportunities in the field, this review endeavors to stimulate further innovation and adoption of biodegradable fibers. It seeks to unlock their potential and contribute to the realization of a more environmentally conscious society.

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“…Rodenburg was also reported as a manufacturer of PBAT in the past [82]. The FDCA analog PBAF is also under development [127,128].…”

Section: Phasmentioning

confidence: 99%

A Review on Melt-Spun Biodegradable Fibers

Naeimirad,

Krins,

Gruter

2023

Sustainability

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“…While copolymerization modification can effectively solve the problems brought by co-modification, there are fewer studies on copolymerization modification for PBAT [ 28 , 29 , 30 ]. Zhang Wei et al [ 31 ] prepared PEF/PBAT block copolymers by esterification polycondensation, and the copolymers produced had good thermal stability, and the tensile strength, Young’s modulus and elongation at break were improved.…”

Section: Introductionmentioning

confidence: 99%

Synthesis and Characterization of Poly(butylene glycol adipate-co-terephthalate/diphenylsilanediol adipate-co-terephthalate) Copolyester

Ge,

Wang,

et al. 2024

Polymers

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The copolyester poly(butylene glycol adipate-co-terephthalate/diphenylsilanediol adipate-co-terephthalate) (PBDAT) was synthesized by the melt polycondensation method using terephthalic acid, adipic acid, 1,4-butanediol, and diphenylsilylene glycol as the raw materials. The molecular chain structure, thermal properties, thermal stability, mechanical properties, and degradation behaviors of the copolyesters were investigated. The results showed that the prepared PBDAT copolyesters exhibited good thermal stability and mechanical properties. With the increase in diphenylsilanediol (DPSD) content, the thermal stability of PBDAT and the melting temperature both increased. The tensile strength and elastic modulus of PBDAT also exhibited an increasing tend. When the DPSD content was 12.5% (PBDAT-12.5), the tensile strength, the elastic modulus, and elongation at break were 30.56 MPa, 238 MPa, and 219%, respectively. With the increase in diphenylsilanediol content, the hydrophilicity of PBDAT decreased, but PBDAT still shows good degradability and the thermal degradation T5% temperature was 355 °C. The thermal degradation of PBDAT was also improved.

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