Synthesis and characterization of luminescent poly(ester-imide) derivatives constituted of alternating spirobifluorene moiety

Covering: 2010-Aug. 2016In an effort towards enhancing function and sustainability, natural products have become of interest in the field of polymer chemistry. This review details the blending of chemistries developed through synthetic organic chemistry and polymer chemistry. Through synthetic organic chemical transformations, such as functional group interconversion, a protection/deprotection series, or installation of a functional group, various designs towards novel, synthetic, bio-based polymer systems are described. This review covers several classifications of natural products - oils and fatty acids, terpenes, lignin, and sugar derivatives - focusing on exploring monomers prepared by one or more synthetic steps.

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Synthesis and characterization of novel anti-inflammatory poly(spiro thiazolidinone)s

Abdelrahman

Hussein

2016

Designed Monomers and Polymers

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A new series of spirothiazolidinone polymers has been accomplished by solution polycondensation of 4,12-dioxa-1,9-dithiadispiro[4.2.4.2]tetradecane-3,11-dione (3) with different aliphatic and aromatic diamines. A model compound 4 was prepared by the reaction of spiro-monomer 3 with benzyl amine and was characterized by elemental and spectral analyses. These polymers were characterized by elemental and spectral analyses. The thermal properties of these polymers were investigated by thermogravimetric analysis and differential thermal analysis measurements. The morphological properties of selected polymers 5c and 5e were tested using scanning electron microscope to study their surface morphology. The molar masses of polymers 5a, 5b, and 5d were determined by gel permeation chromatography. In addition, the anti-inflammatory activities were studied for these spiro-polymers in comparison with the model compound by determination in vivo using acute carrageenan-induced paw edema in rats.

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Synthesis and characterization of luminescent poly(ester-imide) derivatives constituted of alternating spirobifluorene moiety

Cited by 3 publications

References 18 publications

Doping process effect of polyaniline doped with poly(styrenesulfonic acid) supported platinum for methanol oxidation

Doping process effect of polyaniline doped with poly(styrenesulfonic acid) supported platinum for methanol oxidation

Monomer design strategies to create natural product-based polymer materials

Synthesis and characterization of novel anti-inflammatory poly(spiro thiazolidinone)s

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