Synthesis and characterization of manganese ferrite nanoparticles obtained by electrochemical/chemical method

Mazarío, Eva; Mayoral, Álvaro; Salas, E.; Menéndez, Nieves; Herrasti, P.; Sánchez-Marcos, J.

doi:10.1016/j.matdes.2016.09.031

Cited by 51 publications

(31 citation statements)

References 20 publications

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“…The acquirement of the desired physical and chemical properties from metal oxide NPs requires an effective preparation method and has become a significant subject of research. There are several nonconventional techniques in order to achieve high quality metal oxide nanoparticles that have been used or are under development for preparing ultrafine nanostructures [7][8][9][10][11][12][13][14][15][16][17][18]. Numerous factors and various precipitation agents were utilized to synthesis magnetic metal oxide nanocrystals with specific structures.…”

Section: Introductionmentioning

confidence: 99%

Structure and Physical Properties of NiO/Co3O4 Nanoparticles

Naseri

Dehzangi²,

Kamari

et al. 2016

Metals

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Abstract:The thermal treatment method was employed to prepare nickel-cobalt oxide (NiO/Co 3 O 4 ) nanoparticles. This method was attempted to achieve the higher homogeneity of the final product. Specimens of nickel-cobalt oxide were characterized by various experimental techniques, including X-ray diffraction (XRD), transmission electron microscopy (TEM) and Fourier transform infrared spectroscopy (FTIR). X-ray diffraction results showed that there was no crystallinity in the predecessor, and it still had the amorphous phase. The formations of the crystalline phases of the nickel-cobalt oxide nanoparticles started from 350-500˝C, and the final products had different crystallite sizes ranging from 11-35 nm. Furthermore, the variation of DC conductivity (σ dc ), impedance, tangent loss (tgδ) and dielectric constant (ε 1 ) of the calcined specimens with frequency in the range of 10 2 -10 6 Hz was investigated. σ dc showed a value of 1.9ˆ10´6 S/m, 1.3ˆ10´6 S/m and 1.6ˆ10´6 S/m for the specimens calcined at 350, 400 and 450˝C, respectively. Additionally, a decrease in tgδ values with an increase in temperature was observed. Finally, the formed nanoparticles exhibited ferromagnetic behaviors, which were confirmed by using a vibrating sample magnetometer (VSM).

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Section: Introductionmentioning

confidence: 99%

Structure and Physical Properties of NiO/Co3O4 Nanoparticles

Naseri

Dehzangi²,

Kamari

et al. 2016

Metals

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“…Manganese ferrite nanoparticles were prepared in one step, following the methodology given elsewhere, 11 using foils of iron and manganese as anodes and a counter-electrode of iron as the cathode. These materials were purchased from Goodfellow; the Fe purity was 99.5% and 99.9% for the Mn anodes.…”

Section: ■ Introductionmentioning

confidence: 99%

High Specific Absorption Rate and Transverse Relaxivity Effects in Manganese Ferrite Nanoparticles Obtained by an Electrochemical Route

et al. 2015

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Superparamagnetic iron oxide-based nanoparticles (SPIONS) have attracted an enormous amount of attention for their potential use in biomedical applications, due to their good biocompatibility and low toxicity. The current study considers citric acidconjugated manganese ferrite and its synergy to be used in MRI and in hyperthermia treatment, thus showing theragnostic applications. High colloidal stability was obtained with this functionalization. SPIONS with superparamagnetic behavior of crystal sizes of approximately 20 nm were obtained via an electrochemical synthesis method. One of the highest specific absorption rate (SAR) values was achieved in this work (1661 W g −1 ), under a magnetic field of 30 mT at 717 kHz frequency, compared with other magnetic ferrites in the literature. These nanoparticles dissipate heat through Neél relaxation and, together with the high SAR value obtained, indicate an excellent material for hyperthermia treatment of cancer. In addition, these nanoparticles exhibit transverse relaxivity behavior, with an r 2 value of 394 mM −1 s −1 , i.e., at least two times higher than the value of a commercial magnetic contrast agent based on iron oxides. Finally, no toxicity effects of these nanoparticles are evidenced; as a result, these nanoparticles are appropriate for in vivo application.

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“…The average size of the MNPs is 93 ± 5 nm. This size is much larger than manganese ferrite NPs reported earlier for the purpose of MRI or other biomedical objective (Lemarchand et al 2004;Leal et al 2015;Beeran et al 2015;Kang et al 2004;Li et al 2004;Giri et al 2012;Mazarío et al 2016). The hydrodynamic diameter of the CD-PEG-MNPs can be determined by dynamic light scattering (DLS) measurements.…”

Section: Characterization Of Magnetic Nanoparticlesmentioning

confidence: 83%

Cyclodextrin–PEG conjugate-wrapped magnetic ferrite nanoparticles for enhanced drug loading and release

et al. 2018

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Magnetic nanoparticles are envisaged to overcome the impediments in the methods of targeted drug delivery and hence cure cancer effectively. We report herein, manganese ferrite nanoparticles, coated with β-cyclodextrin-modified polyethylene glycol as a carrier for the drug, camptothecin. The particles are of the size of ~ 100 nm and they show superparamagnetic behaviour. The saturation magnetization does not get diminished on polymer coverage of the nanoparticles. The β-cyclodextrin-polyethylene glycol conjugates are characterized using NMR and mass spectrometric techniques. By coating the magnetic nanoparticles with the cyclodextrin-tethered polymer, the drug-loading capacity is enhanced and the observed release of the drug is slow and sustained. The cell viability of HEK293 and HCT15 cells is evaluated and the cytotoxicity is enhanced when the drug is loaded in the polymer-coated magnetic nanoparticles. The noncovalent-binding based and enhanced drug loading on the nanoparticles and the sustained release make the nanocarrier a promising agent for carrying the payload to the target.

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Synthesis and characterization of manganese ferrite nanoparticles obtained by electrochemical/chemical method

Cited by 51 publications

References 20 publications

Structure and Physical Properties of NiO/Co3O4 Nanoparticles

Structure and Physical Properties of NiO/Co3O4 Nanoparticles

High Specific Absorption Rate and Transverse Relaxivity Effects in Manganese Ferrite Nanoparticles Obtained by an Electrochemical Route

Cyclodextrin–PEG conjugate-wrapped magnetic ferrite nanoparticles for enhanced drug loading and release

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