2010
DOI: 10.1021/cm100514r
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Synthesis and Electropolymerization of Hexadecyl Functionalized Bithiophene and Thieno[3,2-b]thiophene End-Capped with EDOT and EDTT Units

Abstract: This version is available at https://strathprints.strath.ac.uk/28454/ Strathprints is designed to allow users to access the research output of the University of Strathclyde. Unless otherwise explicitly stated on the manuscript, Copyright © and Moral Rights for the papers on this site are retained by the individual authors and/or other copyright owners. Please check the manuscript for details of any other licences that may have been applied. You may not engage in further distribution of the material for any pro… Show more

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Cited by 41 publications
(35 citation statements)
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“…Although the wide majority of the crystal structures of alkylthiophene oligomers present anti arrangements of the β torsion angles, some cases in which gauche conformations are preferred have been reported. As for polymers, the only crystal structure in which a gauche conformation has been determined so far is poly(3‐( S )‐2‐methylbutylthiophene), which, however, has a branched side chain.…”
Section: Discussionmentioning
confidence: 99%
“…Although the wide majority of the crystal structures of alkylthiophene oligomers present anti arrangements of the β torsion angles, some cases in which gauche conformations are preferred have been reported. As for polymers, the only crystal structure in which a gauche conformation has been determined so far is poly(3‐( S )‐2‐methylbutylthiophene), which, however, has a branched side chain.…”
Section: Discussionmentioning
confidence: 99%
“…The polymer electrochemically obtained from this monomer was electroactive and showed a low band gap comparable to PEDOT (1.74 eV from optical measurements and 1.53 eV from electrochemistry). 26 Recently, our group has designed novel compounds of EDOT-TT-EDOT type, with different attachments of EDOT units to the TT core, i.e. at 2,5-or 3,6-positions of TT.…”
Section: Introductionmentioning
confidence: 99%
“…Poly(3,4‐ethylenedithiathiophene) (PEDTT), as one of the most studied PEDOT analogues, has unique electrical and optical properties and potential applications in the fabrication of rechargeable batteries, sensors, photovoltaic devices, electrochromic devices, polymer‐fullerene devices, and so on 3, 4–23. In the past 20 years, the electrochemical homopolymerization of compounds containing 3,4‐ethylenedithiathiophene (EDTT) units, as listed in Scheme , has been studied in detail 6, 9–11, 16, 18, 20, 22.…”
Section: Introductionmentioning
confidence: 99%