Synthesis and molecular structures of N,N-dialkyl-4-nitrosoaniline adducts of formally d⁶ metalloporphyrins of ruthenium and cobalt

Interactions of Organic Nitroso Compounds with Metals

“…Metalloporphyrin complexes of Mn, Fe, ,,− Ru, ,, Os, and Co 163 containing C -nitroso ligands have been reported. With the exception of two examples (Fe 161 and Mn 171 ), all the structurally characterized complexes reveal the N -binding mode of the C -nitroso ligand (Table ).…”