Synthesis and properties of the polyanisidines

Koval’chuk, E. P.; Stratan, N.V.; Reshetnyak, Оleksandr; Błażejowski, Jerzy; Whittingham, M. Stanley

doi:10.1016/s0167-2738(01)00748-2

Cited by 34 publications

(24 citation statements)

References 25 publications

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“…23 This pair of peaks can be attributed to radical dication species, 8 and this process is dependent on the pH of the solution. 13 For the polymerization of o-methoxyaniline, all the assumptions made for the polymerization of aniline are accepted. [24][25][26] However, the substituent group may cause some effects that change the reaction, for example, changes in the basicity and mobility of the monomer in the reaction medium.…”

Section: Resultsmentioning

confidence: 99%

“…According to this mechanism, the degree of protonation of polyaniline decreases with increasing oxidation state of the film; for a given oxidation state the protonation increases with increasing acidity of the medium and all polyanilines in base form are insulators, independent of the degree of oxidation. 13 The modified electrodes were conditioned in a solution containing Li + ions for 24 h prior to measurements. The potentiometric measurements were performed in triplicate, with a stabilization time of 1 min.…”

Section: Resultsmentioning

confidence: 99%

“…POMA can be obtained in different oxidation states: leucoemeraldine, emeraldine and pernigraniline; the emeraldine oxidation state can be found as a base (non electrical conductor) or salt (electrical conductor). 13 Conversion from emeraldine base to emeraldine salt can be achieved via protonation in acid medium. Thus these oxidation states are also called undoped and doped, respectively.…”

Section: Introductionmentioning

confidence: 99%

See 2 more Smart Citations

Poly(o-methoxyaniline) modified electrode for detection of lithium ions

Lindino¹,

Casagrande²,

Peiter³

et al. 2012

Quím. Nova

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Recebido em 16/2/11; aceito em 12/9/11; publicado na web em 8/11/11 This paper reports the use of an electrode modified with poly(o-methoxyaniline) for detecting lithium ions. These ions are present in drugs used for treating bipolar disorder and that requires periodical monitoring of the concentration of lithium in blood serum. Poly(omethoxyaniline) was obtained electrochemically by cyclic voltammetry on the surface of a gold electrode. The results showed that the electrode modified with a conducting polymer responded to lithium ions in the concentration range of 1 x 10 -5 to 1 x 10 -4 mol L -1 . The results also confirmed that the performance of the modified electrode was comparable to that of the standard method (atomic emission spectrophotometry).

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Section: Resultsmentioning

confidence: 99%

Section: Resultsmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

See 1 more Smart Citation

Poly(o-methoxyaniline) modified electrode for detection of lithium ions

Lindino¹,

Casagrande²,

Peiter³

et al. 2012

Quím. Nova

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“…Poly-o-anisidine was synthesized by chemical oxidation using ammonium persulfate (APS) in 1 M HCl aqueous solution [11].…”

Section: Structure and Morphologymentioning

confidence: 99%

Synthesis, characterization and electrical conductivity measurement studies of poly-o-anisidine Sn(IV) phosphate [POASn(IV)P] nano-composite cation-exchange material

Khan

2009

Materials Science and Engineering: B

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“…4 Luminol and polyluminol can be considered as monomeric and polymeric analogs of aniline derivatives respectively, which have been the subject of many studies. [5][6][7] Luminol (5-amino-2,3-dihydroxy-1,4-phthalazinedione) is a typical, strong chemiluminescent (CL) reagent that is well known. [8][9][10] In the presence of hydrogen peroxide, a catalyst and an alkaline medium, luminol's maximum emission intensity is about 425 nm, a phenomenon first discovered by Albrecht.…”

Section: Introductionmentioning

confidence: 99%

Synthesis and characterization of chemiluminescent conducting polyluminol via biocatalysis

et al. 2011

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The enzyme catalyzed polymerization of luminol (5-amino-2, 3-dihydroxy-1, 4-phthalazinedione) in the presence of polystyrenesulphonate (SPS) is introduced. Polymerization was achieved using horseradish peroxidase (HRP) as a biocatalyst in a phosphate buffer at pH 8. A green, water-soluble conducting PLUM/SPS complex was obtained. The physico-chemical properties of the product, including possible photoluminescence of the PLUM/SPS complex, were studied. The PLUM/SPS complex was shown to be a chemiluminescent (CL) material that is highly sensitive towards Fe 3+ ions. The quantum yield of the PLUM chemiluminescence was determined to be moderate (0.09 ± 0.01) compared to other chemiluminescent compounds. UV-visible, FTIR, 1 H NMR, GPC and conductivity measurements confirmed that the electroactive form of polyluminol (PLUM) was formed and complexed to the SPS.

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Synthesis and properties of the polyanisidines

Cited by 34 publications

References 25 publications

Poly(o-methoxyaniline) modified electrode for detection of lithium ions

Poly(o-methoxyaniline) modified electrode for detection of lithium ions

Synthesis, characterization and electrical conductivity measurement studies of poly-o-anisidine Sn(IV) phosphate [POASn(IV)P] nano-composite cation-exchange material

Synthesis and characterization of chemiluminescent conducting polyluminol via biocatalysis

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