2021
DOI: 10.1016/j.jssc.2021.122048
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Synthesis and structural characterization of an air and water stable divalent Europium squarate prepared by in situ reduction

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Cited by 3 publications
(14 citation statements)
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“…The Ln–O bond distances for the coordinated waters range from 2.565 to 2.605, 2.506 to 2.582, 2.487 to 2.563, and 2.475 to 2.543 Å for La1, Ce1, Pr1, and Nd1, respectively, while the Ln–O bond distances for the squarate units (O4, O5, O9, and O11) range from 2.512 to 2.588, 2.490 to 2.571, 2.477 to 2.554, and 2.460 to 2.539 Å for La1, Ce1, Pr1, and Nd1, respectively (Table ). All squarate bond distances and angles are consistent with what has previously been reported in the literature. ,, …”
Section: Resultssupporting
confidence: 88%
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“…The Ln–O bond distances for the coordinated waters range from 2.565 to 2.605, 2.506 to 2.582, 2.487 to 2.563, and 2.475 to 2.543 Å for La1, Ce1, Pr1, and Nd1, respectively, while the Ln–O bond distances for the squarate units (O4, O5, O9, and O11) range from 2.512 to 2.588, 2.490 to 2.571, 2.477 to 2.554, and 2.460 to 2.539 Å for La1, Ce1, Pr1, and Nd1, respectively (Table ). All squarate bond distances and angles are consistent with what has previously been reported in the literature. ,, …”
Section: Resultssupporting
confidence: 88%
“…These coordination numbers and geometries are common for trivalent f -element complexes. The observed decrease in coordination number is expected due to the concomitant decrease in ionic radius of the trivalent lanthanides as the series is traversed (i.e., Lanthanide contraction) and is consistent with what is observed in other f -element square complexes. ,,, …”
Section: Discussionsupporting
confidence: 80%
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