1993
DOI: 10.1016/s0040-4039(00)61409-0
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Synthesis and structure elucidation of a novel ecdysteroid, gerardiasterone

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Cited by 24 publications
(8 citation statements)
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“…cause allergic reactions, the symptoms of which are headaches, nose itching, and rashes).291 A sesquiterpene hydrocarbon(403) and a diterpene hydrocarbon(404) were both obtained from a Western Australian Higginsia species 292. The isonitrile(405) from Halichondria sp.293 has been synthesized using an ally1 cyanate-to-isocyanate rearrangement.2g4 Two new linear diterpene diols, (406) and (407), were isolated from the Caribbean sponge Myrmekioderma styx and were shown to be toxic to brine shrimp 295.…”
mentioning
confidence: 99%
“…cause allergic reactions, the symptoms of which are headaches, nose itching, and rashes).291 A sesquiterpene hydrocarbon(403) and a diterpene hydrocarbon(404) were both obtained from a Western Australian Higginsia species 292. The isonitrile(405) from Halichondria sp.293 has been synthesized using an ally1 cyanate-to-isocyanate rearrangement.2g4 Two new linear diterpene diols, (406) and (407), were isolated from the Caribbean sponge Myrmekioderma styx and were shown to be toxic to brine shrimp 295.…”
mentioning
confidence: 99%
“…Osmium-mediated dihydroxylation was only productive with stoichiometric amounts of osmium tetroxide in a pyridine/water mixture at 65°C. [27] In this way a single diol 29 was obtained. From 1 H NMR NOE measurements it was clear that the dihydroxylation had taken place from the more open endo face of the alkene.…”
Section: Second Approach: [2+2] Photocycloaddition Of Allene Butenolidesmentioning
confidence: 99%
“…16 In this way a single diol 16 was obtained. Osmium-mediated dihydroxylation was only productive with stoichiometric amounts of osmium tetroxide in a pyridine/ water mixture at 65 ЊC.…”
Section: Scheme 1 Retrosynthesis Of Solanoeclepin a (Arbitrary Protecmentioning
confidence: 99%
“…Osmium-mediated dihydroxylation was only productive with stoichiometric amounts of osmium tetroxide in a pyridine/ water mixture at 65 ЊC. 16 In this way a single diol 16 was obtained. From 1 H NMR NOE measurements it was clear that the dihydroxylation had taken place from the more open endo face of the alkene.…”
Section: Doi: 101039/ B311415ementioning
confidence: 99%