2019
DOI: 10.26434/chemrxiv.8009591.v1
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Synthesis, Characterisation and Water-Gas Shift Activity of Nano-Particulate Mixed-Metal (Al, Ti) Cobalt Oxides

Abstract: The formation of mixed-metal cobalt oxides, representing potential metal-support compounds for cobalt-based catalysts, has been observed at high conversion levels in the Fischer-Tropsch synthesis over metal oxide-supported cobalt catalysts. An often observed increase in the carbon dioxide selectivity at Fischer Tropsch conversion levels above 80% has been suggested to be inter-linked to the formation of water-gas shift active oxidic cobalt species. Mixed-metal cobalt oxides, namely cobalt aluminate and cobalt … Show more

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