2011
DOI: 10.1016/j.saa.2011.07.051
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Synthesis, characterization and biological activity of some new VO(IV), Co(II), Ni(II), Cu(II) and Zn(II) complexes of chromone based NNO Schiff base derived from 2-aminothiazole

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Cited by 47 publications
(12 citation statements)
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“…Its Cu(II) complex possesses tetrahedrally distorted square planar geometry whereas Co(II), Ni(II) and Zn(II) complexes show distorted tetrahedral geometry and VO(IV) complex shows square pyramidal geometry. 55 The azo-Schiff base 61 forms complexes with VO(IV), Co(II), Ni(II), Cu(II) and Zn(II); octahedral geometry is proposed for all those complexes from their electronic spectra and magnetic susceptibilities. The conductance data indicate non-electrolytic nature of the complexes except the VO(IV) one which is electrolytic in nature.…”
Section: Methodsmentioning
confidence: 99%
“…Its Cu(II) complex possesses tetrahedrally distorted square planar geometry whereas Co(II), Ni(II) and Zn(II) complexes show distorted tetrahedral geometry and VO(IV) complex shows square pyramidal geometry. 55 The azo-Schiff base 61 forms complexes with VO(IV), Co(II), Ni(II), Cu(II) and Zn(II); octahedral geometry is proposed for all those complexes from their electronic spectra and magnetic susceptibilities. The conductance data indicate non-electrolytic nature of the complexes except the VO(IV) one which is electrolytic in nature.…”
Section: Methodsmentioning
confidence: 99%
“…The compounds 25 and 1 underwent condensation reaction to form Schiff base 26 in ethanol at room temperature or dry benzene containing 4‐toluenesulfonic acid as catalyst through 1,2‐addition . Condensation followed by 1,4‐addition with solvent was also possible in this case, and the reaction afforded 27 [5,30,31a,b] (Scheme ).…”
Section: Reaction With Nitrogenous Nuclophilesmentioning
confidence: 99%
“…The authors concluded that metal ions increased the lipophilic nature of Tz-36. Furthermore, Schiff bases may involve the formation of a hydrogen bond through the nitrogen atom of azomethine with the active centres of all constituents, causing interference with normal cellular processes [103].…”
Section: Copper Complexes With Tridentate Thiazole Ligandsmentioning
confidence: 99%