Synthesis, characterization and chemical sensor properties of a novel Zn(II) phthalocyanine containing 15-membered dioxa-dithia macrocycle moiety

Bayğu, Yasemin; Çapan, Rıfat; Erdoğan, Matem; Özkaya, Cansu; Açıkbaş, Yaser; Kabay, Nilgün; Gök, Yaşar

doi:10.1016/j.synthmet.2021.116870

Cited by 16 publications

(4 citation statements)

References 38 publications

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“…It can be seen that SPR sensors based on phthalocyanine and porphyrin films are mainly used to detect vapors of volatile organic compounds, such as chlorinated hydrocarbons, acetic acid, and amines. The detection limit of these compounds for most sensors is units or tens of ppm, which is lower than for electrical and gravimetric sensors based on films of similar phthalocyanines and porphyrins [10,116,117]. At the same time, the response and regeneration times are only a few seconds, which is better than in their case.…”

Section: Current Issues and Future Scopementioning

confidence: 93%

Phthalocyanine and Porphyrin Derivatives and Their Hybrid Materials in Optical Sensors Based on the Phenomenon of Surface Plasmon Resonance

Basova

2024

Chemosensors

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In this review, the state of research over the past fifteen years in the field of the applications of metal phthalocyanines and porphyrin derivatives as well as their hybrid materials with carbon nanotubes, metal oxides, and polymers in optical sensors based on the phenomenon of surface plasmon resonance (SPR) is analyzed. The first chapter of the review presents an analysis of works on the use of porphyrins and phthalocyanines in classical SPR sensors for the detection of gases and volatile organic vapors, as well as their improved modifications, such as total internal reflection ellipsometry (TIRE) and magneto-optical SPR (MOSPR) methods, while the second chapter is devoted to their application for the detection of various analytes in solutions. The third chapter of the review summarizes publications describing recent advances in the use of porous materials based on hybrids of carbon nanotubes and oxides with metal phthalocyanines. The fourth chapter describes two-dimensional metal-organic frameworks (MOFs) based on metal porphyrin derivatives as SPR sensitizers.

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Section: Current Issues and Future Scopementioning

confidence: 93%

Phthalocyanine and Porphyrin Derivatives and Their Hybrid Materials in Optical Sensors Based on the Phenomenon of Surface Plasmon Resonance

Basova

2024

Chemosensors

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“…NO 2 , NO, NH 3 , and Cl 2 ) [17][18][19][20][21] and vapors of volatile organic compounds (VOC). 22 Among the listed gases, phthalocyanines are often used to detect ammonia in the air. Ammonia is classified as an extremely hazardous substance, and is subjected to strict monitoring of its concentration in the environment and industry in the production of fertilizers, household cleaning products and refrigerants.…”

Section: Introductionmentioning

confidence: 99%

Films of substituted zinc phthalocyanines as active layers of chemiresistive sensors for ammonia detection

Ivanova,

Klyamer,

Tunç

et al. 2023

New J. Chem.

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“…Phthalocyanines and their metal complexes are widely used a wide range of areas for a long time beacuse of their matchless electronic properties of the phthalocyanine core, high degree of aromaticity and the ability to be added different substituents. Their applications such as non-linear optical devices [2], sensors [3], liquid crystals [4], dye-sensitized solar cells (DSSCs) [5], Langmuir-Blodgett films [6], and photodynamic therapy [7] can be showed as example. Phthalocyanines are generally soluble in commonly used organic solvents due to substituents such as alkyl, alkoxy, crown ethers.…”

Section: Introductionmentioning

confidence: 99%

Synthesis and Characterization of Novel Water-Soluble Tetra-Substituted Zn(II) Phthalocyanine Containing Triazole and Galactose Moieties

Bayğu

2023

Sakarya University Journal of Science

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In this study, new water-soluble non-peripheral tetra-substituted zinc complex of phthalocyanine which is contain galactose moieties was synthesized. ZnPc-I was prepared from the galactose substituted dicyano compound by the cyclotetramerization reaction. This dicyano compound was synthesized by Click reaction between 3-(pent-4-yn-1-yloxy)phthalonitrile and 6-azido-6-deoxy1,2:3,4-di-O-isopropylidene-α-D-galactopyranose. ZnPc-II was obtained by hydrolysis of the protected isopropylidene groups in ZnPc-I in TFA and water mixture. The galactose linked Zn(II) phthalocyanine was achieved to dissolve in common polar solvents and water. All of the new compounds were characterized by elemental analysis, 1H NMR, 13C NMR, IR, UV–vis and MS spectral data.

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Synthesis, characterization and chemical sensor properties of a novel Zn(II) phthalocyanine containing 15-membered dioxa-dithia macrocycle moiety

Cited by 16 publications

References 38 publications

Phthalocyanine and Porphyrin Derivatives and Their Hybrid Materials in Optical Sensors Based on the Phenomenon of Surface Plasmon Resonance

Phthalocyanine and Porphyrin Derivatives and Their Hybrid Materials in Optical Sensors Based on the Phenomenon of Surface Plasmon Resonance

Films of substituted zinc phthalocyanines as active layers of chemiresistive sensors for ammonia detection

Synthesis and Characterization of Novel Water-Soluble Tetra-Substituted Zn(II) Phthalocyanine Containing Triazole and Galactose Moieties

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