Synthesis, Characterization and DNA Cleavage Activity of the Coordination Polymer {[Cu(phen)(azpy)(NO3)(H2O)]·(NO3)}n

Baraskar, Mukta B.; Kawade, Vitthal A.; Bhat, Satish S.; Butcher, Ray J.; Mohite, Manali; Deshmukh, Nikita; Kumbhar, Avinash S.

doi:10.1007/s10870-022-00923-7

J Chem Crystallogr

2022

DOI: 10.1007/s10870-022-00923-7

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Synthesis, Characterization and DNA Cleavage Activity of the Coordination Polymer {[Cu(phen)(azpy)(NO3)(H2O)]·(NO3)}n

Mukta B. Baraskar

Vitthal A. Kawade

Satish S. Bhat

et al.

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Cited by 3 publications

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“…As a further indication of the scope of Jerry's research and the affection in which he was held by collaborators around the world, this special issue is being published in parallel with another in the Journal of Chemical Crystallography. The papers in that journal reflect more of Jerry's scientific interests including copper compounds, 1,2,4-triazoles, hydrogen and halogen bonding and other interactions, computational studies and pharmaceuticals (Amaral et al, 2022;Baraskar et al, 2022;Bhattacharjee et al, 2021;Boehm et al, 2022;Bu ¨lbu ¨l et al, 2021;Davies et al, 2022;Elshani et al, 2022;Kumari et al, 2022;Lobana et al, 2021;Lopez et al, 2021;Peloquin et al, 2022;Satheesh et al, 2022;Singh et al, 2022).…”

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Foreword to the special virtual issue in tribute to Jerry P. Jasinski

Manke¹,

Zeller²,

Butcher³

2022

Acta Cryst E

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When people think of science and scientists, often the picture of a lone genius, or of a renaissance man comes to mind. Somebody who, being extraordinary but not well understood, overcomes all obstacles on their own. Such times, even if we cherish the thought, are long gone. Today science, and crystallography even more so than most, is done in collaboration, with teams of people spanning many universities, countries, and continents, with each member contributing their unique abilities, joining together to solve today's challenges. Alone, we are little compared to what we can achieve together.Even among those masses that are each a small wheel that keeps the gears moving, there are unique and extraordinary people who stand out. People like Jerry P. Jasinski. People who take collaboration and service for others to a new level. Crystallography is, by its nature, something rarely done in a vacuum; most crystallographers routinely work and collaborate with others. But even in this field, Jerry Jasinski has been one of a kind. Those who knew him can confirm, he never said no when asked for help. He always stepped in, helped out, explained how things worked, and sparked the curiosity of others. The people Jerry worked with spanned the globe. From colleagues in the US, just down the road from Keene State, to research groups from dozens of countries from all inhabited continents of this planet.Jerry was born in Newport, New Hampshire, obtained his BA from the University of New Hampshire, did graduate work at UNH and Worcester Polytechnic Institute and obtained his PhD from the University of Wyoming. He worked as a secondary school teacher of chemistry and physics in New York, Vermont and New Hampshire, and eventually started as an Assistant Professor of Chemistry at Keene State College in 1978, where he remained for the rest of his career. In 1989, Jerry established the New England Molecular Structure Center with NSF funding, and thereafter established a framework for others to follow on doing crystallographic research at an undergraduate institution. His accomplishments are too long to list (Butcher, 2022), but his impact is evident on all who worked with him.Jerry was known throughout the New England chemistry community, most notably as Chair of the Northeastern Section of the American Chemical Society and the president of the New England Institute of Chemists. Beyond his very active involvement in professional societies, Jerry was known by all he interacted with as a caring and selfless man who would gladly put out his hand to help others. He touched chemists in High Schools, students and teachers, in Universities, students and faculty, and took special pride in helping younger chemists progress. His kind heart and boisterous laugh will be sadly missed.Jerry was a prolific scientific author and a strong contributor to Acta Crystallographica, having published 365 articles in this journal alone! He also served as a Co-editor from 2009-2012 and was always happy to help authors to improve their submissions. To honor his me...

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confidence: 99%

Foreword to the special virtual issue in tribute to Jerry P. Jasinski

Manke¹,

Zeller²,

Butcher³

2022

Acta Cryst E

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High‐Performance Azo Cathodes Enabled by N‐Heteroatomic Substitution for Zinc Batteries with a Self‐Charging Capability

Du,

Chen,

Zhang

et al. 2024

Angewandte Chemie

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Redox‐active azo compounds are emerging as promising cathode materials due to their multi‐electron redox capacity and fast redox response. However, their practical application is often limited by low output voltage and poor thermal stability. Herein, we use a heteroatomic substitution strategy to develop 4,4’‐azopyridine. This modification results in a 350 mV increase in reduction potential compared to traditional azobenzene, increasing the energy density at the material level from 187 to 291 Wh kg−1. The introduced heteroatoms not only raise the melting point of azo compounds from 68 °C to 112 °C by forming an intermolecular hydrogen‐bond network but also improves electrode kinetics by reducing energy band gaps. Moreover, 4,4’‐azopyridine forms metal‐ligand complexes with Zn2+ ions, which further self‐assemble into a robust superstructure, acting as a molecular conductor to facilitate charge transfer. Consequently, the batteries display a good rate performance (192 mAh g−1 at 20 C) and an ultra‐long lifespan of 60,000 cycles. Notably, we disclose that the depleted batteries spontaneously self‐charge when exposed to air, marking a significant advancement in the development of self‐powered aqueous systems.

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High‐Performance Azo Cathodes Enabled by N‐Heteroatomic Substitution for Zinc Batteries with a Self‐Charging Capability

Du,

Chen,

Zhang

et al. 2024

Angew Chem Int Ed

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Synthesis, Characterization and DNA Cleavage Activity of the Coordination Polymer {[Cu(phen)(azpy)(NO3)(H2O)]·(NO3)}n

Cited by 3 publications

References 60 publications

Foreword to the special virtual issue in tribute to Jerry P. Jasinski

Foreword to the special virtual issue in tribute to Jerry P. Jasinski

High‐Performance Azo Cathodes Enabled by N‐Heteroatomic Substitution for Zinc Batteries with a Self‐Charging Capability

High‐Performance Azo Cathodes Enabled by N‐Heteroatomic Substitution for Zinc Batteries with a Self‐Charging Capability

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