Dalton Trans.
 2025
DOI: 10.1039/d4dt03261f
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Synthesis, characterization and functionalization of titanium κ1N amidinato complexes from carbodiimides

Marcel Eilers,
Saskia Bültena,
Kevin Schwitalla
et al.

Abstract: A series of titanium amidinato complexes were synthesized by stoichiometric insertion reactions of carbodiimides into bis(π-η5:σ-η1-pentafulvene)titanium complexes. NMR studies and single-crystal X-ray diffraction showed κ1N coordination of the former carbodiimides...

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