Abstract:This article presents a combined experimental and computational study of Ru(II) complex containing 2,5-pyridinedicarboxylic acid ligand. The novel complex [Ru(py-2,5-COOH) 2 (PPh 3 ) 2 ]Á3H 2 O has been obtained in the reaction of [RuCl 2 (PPh 3 ) 3 ] with 2,5-pyridinedicarboxylic acid in methanol and has been studied by IR, 1 H, 31 P NMR, UV-Vis spectroscopy, and X-ray crystallography. The electronic structure of [Ru(py-2,5-COOH) 2 (PPh 3 ) 2 ] has been calculated with the density functional theory (DFT) meth… Show more
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