1995
DOI: 10.1021/ma00122a044
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Synthesis, Characterization, and Polymerization of Glycidyl Methacrylate Derivatized Dextran

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Cited by 366 publications
(310 citation statements)
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“…The availability of dextran with different molecular weights, its solubility in polar organic solvents, which enables chemical modification, and its biocompatibility make this natural polysaccharide synthetically useful. For example, dextran-based hydrogels have been obtained either in a single step using bi-functional crosslinking agents such as isocyanate-type monomers [8], or in two-steps involving the derivatization of dextran with polymerizable double bonds followed by radical [9] or UV [10][11][12] polymerization of the dextran derivatives. Although an extensive study was undertaken, few reports [13] dealt with regioselectivity in chemical modification.…”
Section: Introductionmentioning
confidence: 99%
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“…The availability of dextran with different molecular weights, its solubility in polar organic solvents, which enables chemical modification, and its biocompatibility make this natural polysaccharide synthetically useful. For example, dextran-based hydrogels have been obtained either in a single step using bi-functional crosslinking agents such as isocyanate-type monomers [8], or in two-steps involving the derivatization of dextran with polymerizable double bonds followed by radical [9] or UV [10][11][12] polymerization of the dextran derivatives. Although an extensive study was undertaken, few reports [13] dealt with regioselectivity in chemical modification.…”
Section: Introductionmentioning
confidence: 99%
“…Nonetheless, regioselectivity may be necessary to provide highly ordered, swellable and strong hydrogels [14]. Moreover, few attempts [4,8,9] were made to fully characterize the three-dimensional hydrogel structures, despite the need to obtain information on the crosslink density, the molecular weight between crosslinks, and the average mesh pore size of the gels to enable useful and tailorable hydrogel synthesis to be performed.…”
Section: Introductionmentioning
confidence: 99%
“…They suggested that the reaction occurred through the opening of the GMA epoxy ring (Martens and Anseth, 2000). Van Dijk-Wolthuis et al, 1995 andLo &Jiang, 2010, have investigated the chemical modification of dextran with GMA in DMSO as a solvent catalyzed by 4-(N, N-dimethylamino) pyridine (DMAP). They concluded that the addition of GMA to dextran might occur through the opening of the GMA epoxy ring, too.…”
Section: Introductionmentioning
confidence: 99%
“…They concluded that the addition of GMA to dextran might occur through the opening of the GMA epoxy ring, too. They found glycidol as a by-product, which resulted in the addition of methacrylate groups (Van Dijk-Wolthuis et al, 1995 andLo &Jiang, 2010). However, it was postulated that the trans-esterification reaction would be mainly favored because the formed glycidol is a good leaving group (Van Dijk-Wolthuis et al, 1995).…”
Section: Introductionmentioning
confidence: 99%
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