Synthesis, characterization and the nonlinear optical properties of newly synthesized 4-((1,3-dioxo-1-phenylbutan-2-yl)diazenyl)benzenesulfonamide

Sultan, H.A.; Dhumad, Adil Muala; Hassan, Qusay M.A.; Fahad, Tarek A.; Emshary, C.A.; Raheem, Nabeel A.

doi:10.1016/j.saa.2021.119487

Cited by 44 publications

(11 citation statements)

References 58 publications

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“…Each structure is optimized with DFT@B3LYP/6-31G(d,p) (Singh et al 2021;Sultan et al 2021;Liu et al 2021b) and then both IR and Raman spectra are reproduced as well.…”

Section: Calculations Detailsmentioning

confidence: 99%

Exploring the electronic, optical, and bioactive properties for new modified fullerenes via molecular modeling

et al. 2022

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Pristine fullerene characters are highly influenced upon surface decoration by COOH, NH2, and Li sets. The electronic, vibrational, and optical properties of pristine and modified fullerenes are well tested using DFT. QSAR descriptors are fulfilled via PM6 interface for proposed fullerenes. Results showed that C60-2Li may compete recent kesterite Cu2ZnGeSe4 solar cell which have band gap range as 1.5~1.7 eV and efficiency > 14%. The C60-2Li may represent a new row of highly efficient fabricated solar cells.MESP contours found that additive Li possesses a blue shift in Fullerene electronegative behavior towards electrophilic additions whereas additive COOH and NH2 maintain the original nucleophilic additions. Based upon QSAR values, C60-2NH2 is acknowledged as potential bioactive substrate for drug delivery. This paves the way towed multidisciplinary application of the studied fullerene system.

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“…Each structure is optimized with DFT@B3LYP/6-31G(d,p) (Singh et al 2021;Sultan et al 2021;Liu et al 2021b) and then both IR and Raman spectra are reproduced as well.…”

Section: Calculations Detailsmentioning

confidence: 99%

Exploring the electronic, optical, and bioactive properties for new modified fullerenes via molecular modeling

et al. 2022

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“…Based on the SPM and generally on the spatial self-phase modulation (SSPM) two types of interferences occur viz., destructive and constructive within the laser beam leads to a set of circular diffraction ring patterns (DRPs) depending on the laser beam power. SSPM has been extensively studied in different materials that suffer thermal-dependent changes in their index of refractions [12][13][14][15][16][17][18][19][20][21][22], liquid crystals [23], atomic vapors [24], photorefractive crystals [25], Kerr media [26], and nanosheet dispersion [27]. The number of rings per pattern generally depends on the nonlinear phase shift of the laser beam suffered during the passage through the nonlinear media.…”

Section: Introductionmentioning

confidence: 99%

Synthesis, DFT calculations and optical nonlinear properties of two derived Schiff base compounds from ethyl-4-amino benzoate

et al. 2022

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Two Schiff base compounds viz., Ethyl (E)-4-((3-ethoxy-2-hydroxybenzylidene)amino)benzoate(EHB) and Ethyl (E)-4-(((2-hydroxynaphthalen-1-yl)methylene)amino)benzoate(ENB) are synthesized by condensation of ethyl-4-amino benzoate with 2-hydroxy-3-ethoxy benzaldehyde and 2-hydroxy-1-naphthaldehyde. The two compounds are studied and identified by FT-IR, UV-visible, Mass, 1H-NMR and 13C-NMR spectroscopies. The nonlinear refractive index (NRI) of the two compounds are determined, for ENB compound via the diffraction ring patterns (DRPs) and the Z-scan and via Z-scan for the EHB compound, using continuous wave (cw) low power laser beam, and founds of the order of 10-7 cm2/W due to the first technique and 10-8 cm2/W due to the second technique. The optical limiting (OLg) property of both compounds is studied too with OLg thresholds of 16.5 mW and 11 mW for the compounds EHB and ENB respectively, which makes these two compounds as candidates to be used as an optical limiter (OLr). The DRPs are numerically simulated based on the theory of Fresnel-Kirchhoff with reasonable agreement compare to the experimental findings.

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“…During the last three decades, there has been great needs for materials with high optical nonlinearities and fast response times which can be used with low power laser beams, [1][2][3][4][5][6][7][8][9][10] in variety of applications such as optical switching, [11,12] imaging processing, [13] data storage, [14][15][16][17] phase conjugation, [18] and optical limiting. [19][20][21][22][23][24][25] When a laser beam with fundamental, TEM 00 , transverse mode and continuous wave (cw) traverses a material, an intensity-dependent refraction index can be observed in the medium.…”

Section: Introductionmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

Synthesis, optical nonlinear properties, and all‐optical switching of curcumin analogues

Faisal

Hassan

Alsalim

et al. 2022

J of Physical Organic Chem

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The curcumin analogues (Cur‐MeS and Cur‐MeO) are synthesized using the 3‐chloroacetyl acetone and aromatic aldehydes reaction. Both compounds are characterized using FTIR, LC‐MS, 1H NMR, and 13C NMR spectroscopies. The geometric optimization and thermodynamic properties of the two compounds are carried out theoretically using DFT. The highest HOMO, lowest LUMO, and Mullikan atom charges of the two compounds are calculated using the B3LYP and CAM‐B3LYP methods which are hybrid functionals with a 6‐311+G(2d,p) as the basis set. The nonlinear optical (NLO) properties of both compounds are studied using the spatial self‐phase modulation (SSPM) through the diffraction ring patterns (DRPs) and the Z‐scan techniques, using a continuous wave (cw) low power 473 nm laser beam. The index of nonlinear refraction (INR) of both compounds is calculated by the two techniques. The all‐optical switching property of both samples is tested using two visible cw laser beams.

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Synthesis, characterization and the nonlinear optical properties of newly synthesized 4-((1,3-dioxo-1-phenylbutan-2-yl)diazenyl)benzenesulfonamide

Cited by 44 publications

References 58 publications

Exploring the electronic, optical, and bioactive properties for new modified fullerenes via molecular modeling

Exploring the electronic, optical, and bioactive properties for new modified fullerenes via molecular modeling

Synthesis, DFT calculations and optical nonlinear properties of two derived Schiff base compounds from ethyl-4-amino benzoate

Synthesis, optical nonlinear properties, and all‐optical switching of curcumin analogues

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