Synthesis, characterization and thermal decomposition mechanism of new 5-amino-3-hydrazinyl-1H-1,2,4-triazole-based energetic materials

Yang, Zhen-Li; Yao, Ya-Dong; Zhang, Jian-Guo; Xie, Qiang; Liu, Feng; He, Zhi-Wei; Lu, Zu-Jia

doi:10.1016/j.tca.2024.179703

Thermochimica Acta

2024

DOI: 10.1016/j.tca.2024.179703

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Synthesis, characterization and thermal decomposition mechanism of new 5-amino-3-hydrazinyl-1H-1,2,4-triazole-based energetic materials

Zhen-Li Yang,

Ya-Dong Yao,

Jian-Guo Zhang

et al.

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2024

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Cited by 2 publications

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A Review on Chemistry and Methods of Synthesis of 1,2,4‐Triazole Derivatives

Couto Rodrigues,

Silva Moratório de Moraes,

Tavares de Almeida Pinto

et al. 2024

The Chemical Record

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This review provides a comprehensive overview of research on 1,2,4‐triazoles conducted over the last fifteen years. 1,2,4‐Triazoles are highly significant in the pharmaceutical industry, with numerous compounds from this class used clinically as antifungal, antiviral, antibacterial, anti‐inflammatory, and antitubercular agents. Beyond their pharmaceutical relevance, this review also explores their role in material science and agriculture. In material science, 1,2,4‐triazoles are gaining prominence, particularly in the development of energetic materials (EMs), due to their exceptional properties such as thermal stability, coordination ability, and performance comparable to well‐known explosives. Their applications extend to polymers, corrosion inhibitors, and metal‐organic frameworks (MOFs), and they play a significant role in the development of functional materials for sensors, catalysis, and energy storage. Additionally, the review addresses general aspects and synthetic methodologies for the functionalization and construction of the 1,2,4‐triazole ring. Synthetic methods discussed include metalation synthesis, cyclization of hydrazine derivatives, multicomponent reactions, cyclization of amides and amidines, and microwave‐assisted synthesis. Given the significance of the triazole scaffold, its synthesis has garnered considerable attention due to its wide‐ranging applications across various industrial sectors.

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A Review on Chemistry and Methods of Synthesis of 1,2,4‐Triazole Derivatives

Couto Rodrigues,

Silva Moratório de Moraes,

Tavares de Almeida Pinto

et al. 2024

The Chemical Record

View full text Add to dashboard Cite

show abstract

Thermal safety effect of three alkaline impurities on 1, 2, 4-triazole

Pu,

Wang,

Zheng

et al. 2024

Journal of Loss Prevention in the Process Industries

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Synthesis, characterization and thermal decomposition mechanism of new 5-amino-3-hydrazinyl-1H-1,2,4-triazole-based energetic materials

Cited by 2 publications

References 36 publications

A Review on Chemistry and Methods of Synthesis of 1,2,4‐Triazole Derivatives

A Review on Chemistry and Methods of Synthesis of 1,2,4‐Triazole Derivatives

Thermal safety effect of three alkaline impurities on 1, 2, 4-triazole

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