Abstract:<p>The number of M–N bonded divalent group 14 precursors suitable for
atomic layer deposition is limited, in particular for Ge and Pb. A majority of
the reported precursors are dicoordinated, with the only tetracoordinated example
being the Sn(II) amidinate. No such Ge(II) and Pb(II) compounds have been
demonstrated. Herein, we present tetracoordinated Ge(II), Sn(II) and Pb(II) complexes
bearing two sets of the bidentate 1,3-di-<i>tert</i>-butyl triazenide ligands. These
compounds are highly … Show more
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