Synthesis, crystal structure and characterizations of a new 3D porous zinc phosphonate: Zn6[(O3PCH2)2NHC6H11]4·6H2O

Li, Jing; Meng, Lei; Sun, Zhen‐Gang; Liu, Zhongmin; Zhao, Yan; Zhu, Yan‐Yu; Lu, Xin; Liu, Lei; Zhang, Na

doi:10.1016/j.inoche.2007.11.023

Inorganic Chemistry Communications

2008

DOI: 10.1016/j.inoche.2007.11.023

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Synthesis, crystal structure and characterizations of a new 3D porous zinc phosphonate: Zn6[(O3PCH2)2NHC6H11]4·6H2O

Jing Li

Lei Meng

Zhen‐Gang Sun

et al.

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Cited by 14 publications

References 21 publications

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Hydrothermal Synthesis, Crystal Structures, and Thermal Stabilities of Two New Zinc Phosphonates with a Layered and a 3D Framework Structures

Sun

et al. 2009

Zeitschrift anorg allge chemie

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By using ethylenediamine as a structure‐directing agent, two new zinc phosphonates [enH2]0.5Zn[(L)(H2O)]·H2O (1) and [enH2]0.5Zn5[(HL)(L)3(H2O)2]·3H2O (2) (H3L = H2O3PCH(OH)CO2H, en = ethylenediamine), have been synthesised by hydrothermal reaction and structurally characterised by single crystal X‐ray diffraction as well as with infrared spectroscopy, elemental analysis and thermogravimetric analysis. The structure of compound 1 comprises ZnO6 octahedra and CPO3 tetrahedra connected by [O3PCH(OH)CO2]3– to form a 2D layered structure with one‐dimensional channel system along the a axis, and the protonated ethylenediamine cations are being located between two adjacent layers. In compound 2, the connections of alternately arranged ZnO6, ZnO5 polyhedra, and CPO3 tetrahedra result in a 3D framework structure with channels containing the [NH3(CH2)2NH3]2+ cations.

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Hydrothermal Synthesis, Crystal Structures, and Thermal Stabilities of Two New Zinc Phosphonates with a Layered and a 3D Framework Structures

Sun

et al. 2009

Zeitschrift anorg allge chemie

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A facile preparation of Ag2O/P25 photocatalyst for selective reduction of nitrate

Ren

Jia

Zou

et al. 2015

Applied Catalysis B: Environmental

130

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Mixed-solvothermal syntheses, structures and luminescence properties of two new Zn(II) phosphonates with layered and 3D framework structures

Tong

Zhu

Sun

et al. 2011

Inorganica Chimica Acta

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Synthesis, crystal structure and characterizations of a new 3D porous zinc phosphonate: Zn6[(O3PCH2)2NHC6H11]4·6H2O

Cited by 14 publications

References 21 publications

Hydrothermal Synthesis, Crystal Structures, and Thermal Stabilities of Two New Zinc Phosphonates with a Layered and a 3D Framework Structures

Hydrothermal Synthesis, Crystal Structures, and Thermal Stabilities of Two New Zinc Phosphonates with a Layered and a 3D Framework Structures

A facile preparation of Ag2O/P25 photocatalyst for selective reduction of nitrate

Mixed-solvothermal syntheses, structures and luminescence properties of two new Zn(II) phosphonates with layered and 3D framework structures

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