Synthesis, crystal structure and luminescent property of heterometallic d10–d8 porous complex

Twou nique heterometallic cluster organic frameworks, [Cd 4 Mn III 4 Mn II 6 (Tri) 4 (CH 3 COO) 14 (m 4 -O) 2 (m 3 -O) 2 (H 2 O) 2 ] Cd(H 2 O) 2 ·9 H 2 O( 1)a nd Cu[Cd 5 Cu 6 (Tri) 4 (CH 3 COO) 9 (H 2, have been successfully prepared by employing ab ifunctionalt ripodala lcohol ligand as as tructure-directing agent. Crystal structure analyses revealt hat 1 represents ar are example of frameworks constructed from CdÀMn heterometallic chains, and 2 is the first heterometallic MOF based on highest-nuclear CdÀCu heterometallic cluster buildingb locks. Furthermore, the magnetic properties and gas adsorption abilities of 1 and 2 were systematically studied.

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Construction of Two High‐Nuclear 3d‐4d Heterometallic Cluster Organic Frameworks by Introducing a Bifunctional Tripodal Alcohol as a Structure‐Directing Agent

Lin

Zhang

et al. 2019

Chemistry An Asian Journal

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pH-Dependent two novel heteronuclear Cu(II)/Sr(II) coordination polymers constructed from 1,3,5-benzenetricarboxylic acid: Synthesis, crystal structures and properties

Sun

Yin

Pan

et al. 2016

Journal of Molecular Structure

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Design and synthesis of two luminescent Zn(II)-based coordination polymers with different structures regulated by different solvent system

Wen

Liao

et al. 2016

Journal of Molecular Structure

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Synthesis, crystal structure and luminescent property of heterometallic d10–d8 porous complex

Cited by 4 publications

References 22 publications

Construction of Two High‐Nuclear 3d‐4d Heterometallic Cluster Organic Frameworks by Introducing a Bifunctional Tripodal Alcohol as a Structure‐Directing Agent

Construction of Two High‐Nuclear 3d‐4d Heterometallic Cluster Organic Frameworks by Introducing a Bifunctional Tripodal Alcohol as a Structure‐Directing Agent

pH-Dependent two novel heteronuclear Cu(II)/Sr(II) coordination polymers constructed from 1,3,5-benzenetricarboxylic acid: Synthesis, crystal structures and properties

Design and synthesis of two luminescent Zn(II)-based coordination polymers with different structures regulated by different solvent system

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