Synthesis, Crystal Structure and Magnetic Property of a New Binuclear Copper (II) Complex Containing Water Clusters

Liu, Yuqi; Yang, Rui; Wang, Jing; Xu, Xiao‐Jun

doi:10.1007/s10876-014-0754-9

Cited by 1 publication

(2 citation statements)

References 26 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…Within the centrosymmetric cyclic (H 2 O) 6 cluster only three water molecules are crystallographically unique. The hydrogen bond OÁÁÁO distances range from 2.694(9) to 2.920(10) Å (mean value 2.802 Å ), [Co(phen) 2 (CO 3 …”

Section: X-ray Crystallographymentioning

confidence: 99%

“…The 1D water aggregates, chain and tape, can be constructed by an infinite connection of water molecules or by linking of the same or different types of cyclic small water clusters. Tapes described as T6 (2), T8 (2), T4(2)5(2), T4(2)6(2), T4(2)10(2) and others are known [2][3][4][5][6]. Of relevance to the structure reported here is a tape T4(2)6(2) made of fused hexamers and tetramers.…”

Section: Introductionmentioning

confidence: 99%

See 1 more Smart Citation

Assembly of Supramolecular Networks with the Inclusion of T4(2)6(2) Water Tapes and R6 Water Clusters

et al. 2015

View full text Add to dashboard Cite

Two new supramolecular compounds were synthesized and characterized with the formula of [Cu(bipy) 2 (OAc)]Á(DBrS) 1/2 Á5H 2 O 1, [Co(phen) 2 (CO 3 )]Á(DBrS) 1/2 Á 5H 2 O 2 (H 2 DBS = meso-2,3-dibromosuccinic acid; bipy = 2,2'-bipyridine; phen = 1,10-phenanthroline). The crystal structures of complexes were determined by X-ray single-crystal diffraction. Complex 1 represents R6 water clusters and complex 2 stabilizes in a 1D water tape notated T4(2)6(2). For 2, the 2D layer is defined as a 2D (3,4,6)-connected network with the Schläfli symbol of (4Á5Á6) 4 (4 2 Á5Á6Á7 2 )(4 2 Á5) 2 (4 4 Á5 2 Á6 2 Á7 4 Á9 3 ). Results about i.r. spectra and elemental analyses are presented.

show abstract

Section: X-ray Crystallographymentioning

confidence: 99%