Synthesis, crystal structure and magnetic properties of a novel copper(II) complex with sulfoisophthalic acid

Kurc, Teresa; Videnova-Adrabinska, Veneta; Turowska‐Tyrk, Ilona; Duczmal, Marek; Jerzykiewicz, Maria

doi:10.1016/j.molstruc.2013.08.059

Cited by 5 publications

(2 citation statements)

References 94 publications

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“…The characteristic peaks at 1093 and 1294 cm −1 are attributed to the vibrations of the phthalocyanine backbones [ 36 ]. Furthermore, the adsorption peak at 1620 cm −1 belongs to C=N stretching, which proves the existence of phthalocyanine backbones [ 37 ]. The strong peaks found at about 1358 and 1410 cm −1 are attributed to ν(C=N–C=C), and the peak at 1469 cm −1 is ascribed to ν(C=N) [ 38 ].…”

Section: Resultsmentioning

confidence: 99%

Two-Dimensional Bimetallic Phthalocyanine Covalent-Organic-Framework-Based Chemiresistive Gas Sensor for ppb-Level NO2 Detection

et al. 2023

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Two-dimensional (2D) phthalocyanine-based covalent organic frameworks (COFs) provide an ideal platform for efficient and rapid gas sensing—this can be attributed to their regular structure, moderate conductivity, and a large number of scalable metal active centers. However, there remains a need to explore structural modification strategies for optimizing the sluggish desorption process caused by the extensive porosity and strong adsorption effect of metal sites. Herein, we reported a 2D bimetallic phthalocyanine-based COF (COF-CuNiPc) as chemiresistive gas sensors that exhibited a high gas-sensing performance to nitrogen dioxide (NO2). Bimetallic COF-CuNiPc with an asymmetric synergistic effect achieves a fast adsorption/desorption process to NO2. It is demonstrated that the COF-CuNiPc can detect 50 ppb NO2 with a recovery time of 7 s assisted by ultraviolet illumination. Compared with single-metal phthalocyanine-based COFs (COF-CuPc and COF-NiPc), the bimetallic structure of COF-CuNiPc can provide a proper band gap to interact with NO2 gas molecules. The CuNiPc heterometallic active site expands the overlap of d-orbitals, and the optimized electronic arrangement accelerates the adsorption/desorption processes. The concept of a synergistic effect enabled by bimetallic phthalocyanines in this work can provide an innovative direction to design high-performance chemiresistive gas sensors.

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Section: Resultsmentioning

confidence: 99%

Two-Dimensional Bimetallic Phthalocyanine Covalent-Organic-Framework-Based Chemiresistive Gas Sensor for ppb-Level NO2 Detection

et al. 2023

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“…The approach to the supramolecular frameworks employed in this work involves the use the trifunctional linker NaH 2 SIP for the following reasons: it contains two carboxylate groups and one sulfonate group and is one of the most useful multifunctional ligands due to (1) structural rigidity, (2) strong bonding interactions, and (3) a rich diversity of coordination modes that can be utilized for extension of the metal ions into high-dimensional structures. 16 The sulfonate group is generally perceived as a weaker group with respect to its coordinating ability, and it has one more potentially coordinating oxygen atom. The weak coordination nature of sulfonate makes its coordination mode very flexible.…”

Section: Introductionmentioning

confidence: 99%

Syntheses, crystal structures, and fluorescent properties of three coordination polymers with 5-sulfoisophthalic acid anion and 4-phenylpyridine

Chen

Zhou

et al. 2021

Journal of Chemical Research

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Three coordination polymers—{[Ag2(SIP)(4-pp)]·[Ag(4-pp)2]·H2O}n, [Pb4(SIP)2( μ3-OH)2(H2O)2]n, and {[Zn2(SIP)2(4-pp)4][Zn(4-pp)2(H2O)4]·4H2O}n (SIP = 5-sulfoisophthalic acid anion, 4-pp = 4-phenylpyridine)—are constructed under hydrothermal or solvothermal conditions using sodium m-phthalate 5-sulfonate (NaH2SIP) and 4-phenylpyridine as ligands. The structures of the three complexes are determined by single-crystal X-ray diffraction, powder X-ray diffraction, thermogravimetric analyses, Fourier-transform infrared analysis, and photoluminescence. The fluorescent properties of the complexes in the solid state are investigated at room temperature, and the results indicate that they all show photoluminescent properties.

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Synthesis, crystal structure, spectroscopic studies and magnetic behavior of a new diphosphonate-bridged dinuclear copper(II) complex

et al. 2017

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Synthesis, crystal structure and magnetic properties of a novel copper(II) complex with sulfoisophthalic acid

Cited by 5 publications

References 94 publications

Two-Dimensional Bimetallic Phthalocyanine Covalent-Organic-Framework-Based Chemiresistive Gas Sensor for ppb-Level NO2 Detection

Two-Dimensional Bimetallic Phthalocyanine Covalent-Organic-Framework-Based Chemiresistive Gas Sensor for ppb-Level NO2 Detection

Syntheses, crystal structures, and fluorescent properties of three coordination polymers with 5-sulfoisophthalic acid anion and 4-phenylpyridine

Synthesis, crystal structure, spectroscopic studies and magnetic behavior of a new diphosphonate-bridged dinuclear copper(II) complex

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