2006
DOI: 10.1007/s11224-006-9117-y
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Synthesis, crystal structure, and properties of copper(II) and manganese(II) complexes with azide and 3,4-di(2′-pyridyl)-1,2,5-oxadiazole

Abstract: Two transition metal complexes with azide and 3,4-di(2 -pyridyl)-1,2,5-oxadiazole (dpo), [Cu 2 (dpo) 2 (N 3 ) 4 ] (1), and [Mn(dpo) 2 (N 3 ) 2 ] (2), have been synthesized and characterized by single-crystal X-ray diffraction. The Cu(II) complex is binuclear with double end-on (EO) azido bridges, in which each Cu(II) ion assumes a distorted square pyramidal geometry, and each EO azido bridge adopts a quasisymmetric fashion. In contrast, the Mn(II) complex is mononuclear, in which the Mn(II) ion is ligated by t… Show more

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Cited by 10 publications
(1 citation statement)
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“…The pseudohalide azide has been widely utilized as a versatile bridging ligand and as an excellent magnetic coupler and the next article by Liu et al [32] describes the syntheses, crystal structure, and properties of Cu(II) and Mn(II) complexes with azide and 3,4-di(2 0 -pyridyl)-1,2,5-oxadiazole. Whereas the Cu(II) complex is binuclear, the Mn(II) complex is mononuclear.…”
Section: Issuementioning
confidence: 99%
“…The pseudohalide azide has been widely utilized as a versatile bridging ligand and as an excellent magnetic coupler and the next article by Liu et al [32] describes the syntheses, crystal structure, and properties of Cu(II) and Mn(II) complexes with azide and 3,4-di(2 0 -pyridyl)-1,2,5-oxadiazole. Whereas the Cu(II) complex is binuclear, the Mn(II) complex is mononuclear.…”
Section: Issuementioning
confidence: 99%