Synthesis, crystal structure and screening for anticonvulsant and antianxiety activities of three new Ni(II), Cu(II), and Zn(II) dithiocarbamate complexes

Antiproliferative activity of Fe(ii), Co(ii), Ni(ii), Cu(ii), and Zn(ii) complexes of dithiocarbamate: synthesis, structural characterization, and thermal studies

“…Complex 5 is diamagnetic and showed a band at 277 nm which suggests tetrahedral geometry around the Zn( ii ) ion. 16,37,41…”

Design, synthesis, and structural evaluation of metal complexes of azepane-1-carbodithioate for targeting human breast cancer: investigating cytotoxic activity against the MDA-MB-231 cell line

“…These values suggest a distorted tetrahedral geometry around the Zn( ii ) metal ion. 39–42 In the solid state, the crystal structure of the complex is stabilized by C–H⋯S interactions between the dithioate sulfur and CH of the azepane ring (Fig. S16, ESI†), resulting in a linear chain architecture.…”

Exploring the BSA- and DNA-binding, cytotoxicity, and cell cycle evaluation of ternary copper(ii)/diimine complexes with N,N-dibenzyl-N′-benzoylthiourea as promising metallodrug candidates

“…35 The presence of various weak intermolecular hydrogen bonding interactions stabilizing the crystal self-assembly have been observed in several biologically actives copper complexes recently reported. 36,37…”