Synthesis, Crystal Structure and Theoretical Calculation of Ni(II) Complex with N,N′‐1,2‐Cyclohexenylenebis (salicylideneimine)

Bi, Caifeng; Wang, Aidong; Yu, Fan; Zou, Yanna; Zhang, Xia

doi:10.1080/15533170601172518

Cited by 2 publications

(1 citation statement)

References 2 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…Considerable work including theoretical and experimental has concentrated on the family of chiral salen ligands derived from optical pure diamines 1,2-cyclohexanediamine and salicylaldehyde or its derivatives. For most of the transition metals, the corresponding salen Schiff base metal complexes in which tetradentate N 2 O 2 or pentadentate N 2 O 2X coordinate with metal ions have been reported [7][8][9][10][11][12][13] and they display a distorted square planar or square pyramidal geometry. Although the analogy chiral Schiff bases (H 2 L), derivated from chiral diamine and 2-hydroxy-1-naphthalidehyde, and its transition metal complexes have been reported, including ML (M: Ni, Cu, Co, Mn and Zn), most of the structures were proposed on the basis of the compositions and spectroscopic data.…”

Section: Introductionmentioning

confidence: 99%

Synthesis, crystal structure and anticancer activity of 2D-coordination polymer of cerium(III) with chiral Schiff base trans-N,N′-bis-(2-hydroxy-1-naphthalidehydene)-(1R,2R)-cyclohexanediamine

Yu¹,

Wang²,

Bi³

et al. 2011

Synthetic Metals

Self Cite

View full text Add to dashboard Cite

a b s t r a c tThe chiral Schiff base coordination polymer [Ce(H 2 L) 3 (NO 3 ) 3 Ce(H 2 L) 3 (NO 3 ) 3 (H 2 O)] n [H 2 L: trans-N,N -bis-(2-hydroxy-1-naphthalidehy-dene)-(1R,2R)-cyclohexanediamine] was synthesized and characterized by infrared spectroscopy, elemental analysis and single-crystal X-ray diffraction analysis. X-ray crystallography shows that the Ce(III) coordinates with three neutral Schiff base ligands and three nitrates. One Ce(III) is nine-coordinated by three oxygen atoms from three different Schiff base ligands and six oxygen atoms from three nitrates, the other Ce(III) is ten-coordinated because of the coordination of an additional water molecule. Each Schiff base ligand serves as a bridging ligand to link Ce(III) ions through oxygen atoms, leading to a coordination polymer. The Ce(III) coordination polymer displays two dimensional plane grid network structure. The antiproliferation activities of the ligand H 2 L and its Ce(III) coordination polymer on MDA-MB-231 breast cancer cells were also studied by MTT (3-[4,5-dimethyltiazol-2-yl]-2,5-diphenyltetrazolium bromide) method. The results indicate that H 2 L and [Ce(H 2 L) 3 (NO 3 ) 3 Ce(H 2 L) 3 (NO 3 ) 3 (H 2 O)] n can inhibit the cellularproliferation. Moreover, the coordination polymer had higher antiproliferative activity than that of the ligand.

show abstract