Synthesis, crystal structure, magnetic properties and second harmonic generation of a new noncentrosymmetric coordination compound: Triaqua(4-amino-6-methoxypyrimidine) cuprate(II)sulfate

Abstract

The Cu(II) cation is five-coordinated by two nitrogen atoms of the 4-amino-6-methoxypyrimidine ligand and three water oxygen atoms. The ligand molecules and the 5-connected Cu centers link each other to give a 1-D corrugated hybrid chain running along the b-axis direction.