Synthesis, Crystal Structures, and Magnetic Properties of One-dimensional Lanthanide(III)-Octacyanomolybdate(V) Assemblies with 3,4,7,8-Tetramethyl-1,10-phenanthroline as a Blocking Ligand

The synthesis, crystal structure and magnetic properties of a one-dimensional terbium(III)–octacyanidomolybdate(V) assembly

“…As shown in Fig. 6, the field dependence of the magnetization performed at 1.8 K shows a rapid increase in magnetization with field, with a magnetization value of 6.06 N B mol À1 at 70 kOe, corresponding well with the ferromagnetic ground-state spin of 6 m B (Prins et al, 2007;Wang, 2013). Thus, ferromagnetic interactions between Mo V and Tb III ions exist in (I).…”

“…The initial decrease is mainly ascribed to the thermal depopulation of the Stark levels of the Tb III 7 F 6 ground state. The abrupt increase in M T at low temperature indicates that the coupling interaction between metal ions overcomes the depopulation of the ground state, leading to a net spin along the field, but a conclusion cannot be drawn about the magnetic coupling nature (Wang, 2013;Zhou et al, 2010).…”