Synthesis, experimental and theoretical analyses of bis(2-ethylphenyl)phosphorodithioates of nickel(II)

Thallium(i)phosphorodithioates containing intra- and intermolecular π-hole triel bonds

“…The present investigation is an extension of our ongoing research interest in non-covalent interactions. 40–46 We herein designed and characterized two new diaryldithiophosphato- S , S ′-thallium compounds, corresponding to Tl + [S 2 P{OC 6 H 3 (2,5-(CH 3 ) 2 )} 2 ] − ( 1 ) and Tl + [S 2 P{OC 6 H 3 (3,5-(CH 3 ) 2 )} 2 ] − ( 2 ), consisting of a π-hole at the Tl atom, which results in Tl–C/S triel bonds. In this study, we placed particular focus on the self-assembled structures formed by Tl( i )⋯S, Tl( i )⋯C TrBs, anagostic, and other non-covalent interactions.…”

“…17, The present investigation is an extension of our ongoing research interest in non-covalent interactions. [40][41][42][43][44][45][46] We herein designed and characterized two new diaryldithiophosphato-S, S′-thallium compounds, corresponding to Tl + [S 2 P{OC 6 H 3 (2,5-…”

Poly(dithiophosphate)s, a New Class of Phosphorus- and Sulfur-Containing Functional Polymers by a Catalyst-Free Facile Reaction between Diols and Phosphorus Pentasulfide

“…Furthermore, the resulting dialkyl dithiophosphates can also be used for several other purposes, e.g., flotation additive [25], wastewater treatment [26] or reagent in organic reactions [27]. The DTPs possess a strong acidic group, and moreover, their anions are highly efficient metal ion complexing agents due to the two sulfur atoms bound to the phosphorus atom [28]. Thus, it can be presumed that the versatility of these functional groups may enable broad application possibilities, especially when they are involved in macromolecular structures.…”