Synthesis, experimental, theoretical, and molecular dynamic studies of 1-(2,5-dimethoxy-4-methylphenyl)ethan-1-thiosemicarbazone as green inhibitor for carbon steel corrosion

Elqars, Esseddik; Laamari, Yassine; Sadik, Karima; Bimoussa, Abdoullah; Oubella, Ali; Mecnou, Issam; Auhmani, Aziz; Taha, Mohammed A.; Essadki, Abdelhafid; Aboulmouhajir, Aziz; Itto, My Youssef Ait; Nbigui, Taibi

doi:10.1016/j.molstruc.2023.135228

Cited by 15 publications

(1 citation statement)

References 84 publications

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“…Khaled Saad Miled Ferigita has examined the corrosion inhibition of mild steel in acidic media using new oxopyrimidine derivatives: Experimental and theoretical insights [7] synthesis, characterization, experimental and theoretical study of the inhibitory power of new 8-hydroxyquinoline derivatives for mild steel in 1.0 M HCl has been determined by M. Rbaa [8]. Esseddik Elqars has investigated the synthesis, experimental, theoretical, and molecular dynamic studies of 1-(2,5-dimethoxy-4-methylphenyl) ethan-1-thiosemicarbazone as green inhibitor for carbon steel corrosion [9]. Corrosion inhibition study of expired acetazolamide on Mild Steel in dilute hydrochloric acid solution has been reported by Chaudhari, L.P [10].…”

Section: Introductionmentioning

confidence: 99%

Anti-corrosion properties of expired ropinirole (ERN System) drug as inhibitor for mild steel in 1M HCl

Hameed,

Kani,

Mohamed

et al. 2023

Zaštita materijala

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Ropinirole is utilized to forestall sickness and spewing brought about by disease chemotherapy and radiation treatment. It works by hindering serotonin, a characteristic substance in the body that causes queasiness and retching. After lapse, they can be utilized as consumption added substances or inhibitors. The consumption obstruction activity of terminated Ropinirole drug (ERN) on the erosion of mild steel in 1M HCl medium has been assessed by the weight reduction strategy. The weight reduction estimations showed that erosion restraint effectiveness expanded with expanding the convergence of the inhibitor, with greatest security productivity at 0.001 M. The temperature influences the pace of erosion; at high temperatures, the consumption restraint effectiveness diminishes, and erosion is noticed. The robotic parts of consumption obstruction have been concentrated by the potentiodynamic polarization method and electrochemical impedance spectroscopy (EIS). The potentiodynamic polarization strategy uncovers that the inhibitor framework capabilities as a cathodic kind of inhibitor, controlling cathodic responses. An inhibitor can decrease corrosion current due to inhibited reaction rate and increase Linear polarization resistance due to the formation of a barrier on the electrode surface. time., since, within the sight of an inhibitor framework, the charge moves opposition esteem increments and the twofold layer capacitance esteem diminishes. The surface morphology of repressed gentle steel was dissected by filtering electron microscopy (SEM). The natural constituents on the gentle steel surface have been portrayed by energy dispersive X-beam spectroscopy (EDAX). The harshness of the gentle steel surface in cleaned MS, clear MS, and inhibitor frameworks has been described by nuclear power microscopy (AFM). The outcomes have obviously shown that ERN has a repressing limit with regards to decreasing the erosion of gentle steel submerged in hydrochloric corrosive medium.

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Section: Introductionmentioning

confidence: 99%

Anti-corrosion properties of expired ropinirole (ERN System) drug as inhibitor for mild steel in 1M HCl

Hameed,

Kani,

Mohamed

et al. 2023

Zaštita materijala

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A Flexible Asymmetric Supercapacitor with High‐Performance and Long‐Lifetime: Fabrication of Nanoworm‐Like‐Structured Electrodes Based on Polypyrrole‐Thiosemicarbazone Complex

Avcu Altıparmak,

Yazar,

Bal‐Demirci

2024

Small Methods

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A thiosemicarbazone‐based iron(III) complex is prepared and used in the preparation of a supercapacitor electrode material. This electrode is produced by a solvothermal reaction of polypyrrole and the complex on carbon felt. The characterization of the complex and material is carried out using UV‐vis, elemental analysis, FT‐IR, XRD, BET, and TGA methods, and the surface morphology is examined using SEM technique. Because the interaction of electrode and electrolyte is of great importance in energy storage systems, as the surface area and pore volume increase, electrode ions at the electrode/electrolyte interface leak to the inner surfaces and interact with the larger surface area, which increases the charge storage performance. The electrode material, nano‐worm structure, reached the highest specific capacitance value of 764.6 F g−1 at 5 mV s−1. Compared to the capacitance value of polypyrrole in its pure form, it is observed to exhibit an 187.2% increase. The highest specific capacitance value of the asymmetric supercapacitor (ASC) formed with a graphite electrode is 318.1 F g−1 at the current density of 1 Ag−1. Moreover, ASC reached a wide working potential of 1.8 V in an aqueous electrolyte and exhibited ultra‐long cycle life (112%), maintaining its stability after 10 000 cycles.

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Design and synthesis of new triazole derivative as a copper corrosion inhibitor in NaCl solution: a combined electrochemical and theoretical study

Lasri,

Laamari,

Ait-karra

et al. 2024

J Solid State Electrochem

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Synthesis, experimental, theoretical, and molecular dynamic studies of 1-(2,5-dimethoxy-4-methylphenyl)ethan-1-thiosemicarbazone as green inhibitor for carbon steel corrosion

Cited by 15 publications

References 84 publications

Anti-corrosion properties of expired ropinirole (ERN System) drug as inhibitor for mild steel in 1M HCl

Anti-corrosion properties of expired ropinirole (ERN System) drug as inhibitor for mild steel in 1M HCl

A Flexible Asymmetric Supercapacitor with High‐Performance and Long‐Lifetime: Fabrication of Nanoworm‐Like‐Structured Electrodes Based on Polypyrrole‐Thiosemicarbazone Complex

Design and synthesis of new triazole derivative as a copper corrosion inhibitor in NaCl solution: a combined electrochemical and theoretical study

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