2020
DOI: 10.26434/chemrxiv.10312529.v2
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Synthesis, Modular Composition, and Electrochemical Properties of Lamellar Iron SulfidesSynthesis, Modular Composition, and Electrochemical Properties of Lamellar Iron Sulfides

Abstract: Transition metal chalcogenides with layered structures have emerged as promising materials for energy storage, catalysis, and electronics, among other areas. We have identified a new layered phase of iron sulfide containing interlayer solvated cations. We present an optimized synthesis for the Li+-containing material from an Fe(III) xanthate complex. Structure and composition data indicate the material consists of poorly-ordered iron sulfide layers separated by solvated cations. The lamellar spacing in these m… Show more

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