Synthesis of complex sulfide phases BaSm2S4-Tm2S3 and studies of their electrolytic properties

Mikhailichenko, T. V.; Kalinina, L. A.; Ushakova, Yu. N.; Shirokova, G. I.; Tokareva, T. V.

doi:10.1134/s1023193511050089

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“…As objects of studies, we chose sulfide conducting SEs based on CaYb 2 S 4 and BaSm 2 S 4 belonging to the class of alkaline earth thiolanthanates, which can be sulfide ion conductors [1,2]. The influence of the method for the preparation of oxide precursors on the temperature range of sulfide phases, their morphology, and electrophysical and electrochemical properties was studied.…”

Section: Introductionmentioning

confidence: 99%

Effect of the method for the preparation of the oxide precursor on the electrolytic properties of sulfide-conducting solid electrolytes

et al. 2015

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Solid solutions (SSs) based on CaYb 2 S 4 (Yb 3 S 4 structural type) and BaSm 2 S 4 (CaFe 2 O 4 structural type) were prepared using the ceramic and chemical methods for the preparation of oxide precursors. The samples were certified by XRD and electron microscopy. The electric conductivity and thermal stability of the samples were studied. The electron transport numbers were determined by the Hebb-Wagner method.

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Section: Introductionmentioning

confidence: 99%