Synthesis of mesoporous hexagonal titanium aluminophosphate molecular sieves and their catalytic applications

Recent Advances in the Preparation and Application of Mesoporous Aluminophosphate-Based Materials

“…These include the incorporation of Ti into the framework [43][44][45], grafting of Ti onto the surface of pre-formed mesoporous aluminophosphate [46] and the preparation of pure mesoporous TiPO 4 [47]. The incorporation of Ti into the aluminophosphate framework was achieved using CTAC (cetyltrimethlyammonium chloride) as surfactant and titanium isopropoxide as the source of titanium [45].…”

Biomimetic Synthesis and Characterization of Mesoporous Titanium Dioxide

“…Stucky and co-workers were the first to apply the surfactant-assisted procedure to the synthesis of nonsilica based materials [7]. However, all of the templates used were chemical materials [8][9][10][11][12] that were expensive and sometimes could produce harmful by-products. Nano-anatase and mesoporous anatase are often used as additives in cosmetics or other commodities, so it is important to choose a nontoxic, nonpolluted surfactant.…”

Synthesis, characterisation and catalytic properties of vanadium substituted mesoporous aluminophosphates

“…The mechanism involved in the formation of silica based M41S series for the incorporation of silica in AlPO framework was investigated [9]. Attempts have also been made to incorporate transition elements into the framework of mesoporous AlPO [10][11][12][13][14][15][16][17][18]. Recently, Ti-AlPO has been synthesised [12] and demonstrated as potential catalyst for oxidation of various organic substrates with 30% H 2 O 2 .…”